Article
Chemistry, Multidisciplinary
Rui Wang, Shengyu Feng, Hailong Liu, Gang Yi, Dengxu Wang
Summary: Developing a new organosilicon synthetic methodology is significant for the design and synthesis of organosilicon materials with novel structures and functionality. In this study, functionalized disiloxanes were prepared through the oxa-Michael addition reaction, and these compounds exhibited enhanced fluorescence performance compared to analogs lacking Si-O-Si units.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Materials Science, Composites
Runlian Zhong, Zhennan Luan, Siwei Yan, Quande Cui, Fuhao Zhu, Qianqian Qi, Qingguo Wang
Summary: This article prepared advanced biodegradable thermoplastic elastomer (BTPE)/reduced graphene oxide (rGO) nanocomposites using aliphatic diols, aliphatic dibasic acids, and graphene oxide (GO) as raw materials. The rGO is well dispersed in the BTPE matrix through its predispersion in aliphatic diols before the polycondensation of the polyester prepolymers. The addition of GO greatly enhances the tensile strength, elongation at break, biodegradability, and electrical conductivity of the BTPE/rGO nanocomposites.
POLYMER COMPOSITES
(2023)
Article
Chemistry, Multidisciplinary
Haijun Ji, Hui Yang, Yan Wan, Liwei Li, Jiaqi Wang, Xin Zhang, Jie Yu, Xinxin Zhou, Runguo Wang, Liqun Zhang
Summary: In this research, semi-biobased elastomers, poly(dibutyl fumarate-co-butadiene)s (PDBFBs), were synthesized and their properties were examined. The results showed that PDBFB nanocomposites exhibited adequate mechanical strength, good elongation at break, low rolling resistance, and excellent thermoresistant oxygen aging performance, indicating their potential for practical applications. This work provides a green synthesis route for designing sustainable engineering elastomers in the rubber industry.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Polymer Science
Connor J. Hill, Armando G. McDonald, Mark F. Roll
Summary: A novel route to synthesize adamantane substituted diene copolymers using emulsion polymerization was demonstrated, with an improved monomer synthesis method. The high solubility and improved access to 2-(1-adamantyl)-1,3-butadiene provide potential for exploring diene polymers with enhanced high temperature properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Chemistry, Physical
Alina R. Gaidai, Polina V. Vakuliuk, Eugeniy M. Demianenko, Roman B. Kozakevych, Tetiana Murlanova, Iryna M. Furtat, Victor V. Lobanov, Valentin A. Tertykh, Alexander A. Golub
Summary: Comprehensive studies using quantum chemical calculations and IR spectroscopy have shown that the interaction between ornidazole and hydroxylated and functionalized silicas is due to the formation of hydrogen bonds. The highest adsorption energy was observed for hydroxylated silica, followed by aminosilica and silica with methyl groups on the surface. Furthermore, nanocomposites based on hydroxylated, aminated, and partially methylated matrices exhibited the highest degree of release of ornidazole, while nanocomposites based on fully methylated matrices showed a decrease in the release degree.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Qiang Ma, Michael Schmitt, Yijun Zhang, Gautier Schrodj, Loic Vidal, Elea Collanges, Dominique Begin, Jacques Lalevee
Summary: The study successfully utilized photopolymerization synergistic thermal polymerization process to prepare opaque graphene composites, achieving significant improvement in depth of cure through enhanced dual photo/thermally initiated photopolymerization process, allowing customization of product thickness by adjusting time.
MATERIALS CHEMISTRY FRONTIERS
(2022)
Article
Polymer Science
Federica Magaletti, Fatima Margani, Alessandro Monti, Roshanak Dezyani, Gea Prioglio, Ulrich Giese, Vincenzina Barbera, Maurizio Stefano Galimberti
Summary: Elastomer composites with low hysteresis are important for sustainable development. In this study, a furnace carbon black (CB) functionalized with polar groups was used to replace silica, resulting in lower hysteresis. The composites with CB/SP exhibited more efficient crosslinking and higher dynamic rigidity, leading to lower hysteresis.
Article
Polymer Science
Chengqiang Ding, Yuhan Yan, Yuhao Peng, Danming Wu, Hang Shen, Jiandong Zhang, Zhao Wang, Zhengbiao Zhang
Summary: In this study, a well-controlled piezoelectrically mediated reversible addition-fragmentation chain-transfer polymerization (piezoRAFT) was successfully conducted using piezoelectric ZnO nanoparticles as the mechanochemical transducer under ultrasonic agitation. The resulting polymer exhibited high end-group fidelity, low dispersity, and capacity for chain extension. The generation of alkyl radicals through electron transfer process from piezoelectric nanoparticles to alkyl bromide was confirmed by various characterization techniques.
Article
Engineering, Multidisciplinary
Haijun Ji, Hui Yang, Xinxin Zhou, Chaoying Sun, Liwei Li, Shuainan Zhao, Jie Yu, Sai Li, Runguo Wang, Liqun Zhang
Summary: In this study, a new type of bio-based elastomer PDMIBs was successfully synthesized, and its properties were regulated by adjusting comonomer ratios and compositions. The bio-based elastomer exhibited excellent mechanical properties, abrasion resistance, and oil resistance, making it suitable for various engineering applications.
COMPOSITES PART B-ENGINEERING
(2023)
Article
Engineering, Chemical
Hang Hu
Summary: This article demonstrates a novel soft and stretchable electret (PPSE) with great electromechanical performance. The PPSE exhibits a large d33eff value up to 477 pC/N and excellent charge stability, and it is capable of outputting electric signals from twisting, bending, and other mechanical interactions without breaking apart.
POLYMER ENGINEERING AND SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Jae-Young Kim, Hyo-Jun Jang, Eunyoung Jung, Gyutae Bae, Soonwon Lee, Choon-Sang Park, Bhumjae Shin, Heung-Sik Tae
Summary: The effect of adding small amounts of auxiliary gases to PANI nanocomposite films during plasma polymerization at atmospheric pressure was investigated. The addition of argon or nitrogen significantly improves the uniformity and regularity of the films, while adding oxygen weakens these properties. PANI films synthesized with a small amount of nitrogen show the best electrical resistance and resistance changing behavior after external I-2 doping compared to other gases.
Article
Polymer Science
Jiaxian Qiu, Yingrui Bai, Jinsheng Sun, Liyao Dai, Shaofei Lei, Fan Liu
Summary: The study focused on the synthesis method and performance characteristics of an oil-based gel-plugging agent with high structural strength and strong thermal stability, demonstrating its excellent gelling performance and high bearing capacity.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
David Zoltan Pirityi, Tamas Barany, Kornel Poloskei
Summary: This research investigates the effects of nano-reinforcement materials on the mechanical properties of rubber samples. The study finds that precipitated silica can improve the properties of rubber, while a combination of graphene nanoplatelets and carbon black can effectively enhance the tensile strength and elongation at break of rubber. However, the addition of graphene nanoplatelets negatively affects the abrasion resistance of the samples.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
Vincent Bouad, Kohji Ohno, Ahmed Addad, Adeline Marin, Nicolas Donzel, Sophie Barrau, Joel Lyskawa, Vincent Ladmiral
Summary: This article reports the surface-initiated RAFT polymerization of TrFE and VDF from BTO NPs for the preparation of piezoelectric composites. The new xanthate chain transfer agent, DOPA-XA, was immobilized onto BTO NPs to mediate the polymerization. The resulting fluoropolymer-decorated BTO NPs were incorporated into a P(VDF-co-TrFE) matrix, leading to innovative composites for piezoelectric applications.
Article
Polymer Science
Jose Costa de Macedo Neto, Bruno Mello de Freitas, Adalberto Gomes de Miranda, Reinaldo de Almeida Rodrigues, Gilberto Garcia Del Pino, Antonio Claudio Kieling, Marcos Dantas dos Santos, Sergio Duvoisin Junior, Antonio Estanislau Sanches, Israel Gondres Torne, Claudia Candida Silva, Joao Carlos Martins da Costa, Roger Hoel Bello
Summary: The aim of this study was to investigate the stability and morphology of polystyrene latex with kaolinite as a filler during the synthesis of nanocomposites through emulsion polymerization. Nanocomposites with different weight percentages of kaolinite (1%, 3%, and 5%) were prepared. Latexes with 1% to 3% kaolinite showed stability during the polymerization reaction, and the hydrodynamic diameters were measured to be 93.68 nm and 82.11 nm for the latexes with 1% and 3% kaolinite, respectively. XRD, SEM, and HRTEM analysis confirmed the presence of exfoliated and intercalated structures of kaolinite.
Article
Engineering, Chemical
Miao Tian, HuiJuan Xu, Lei Yao, Rong Wang
Summary: A green antimicrobial lysozyme nanofilm was developed and successfully reduced membrane fouling by introducing remarkable antibacterial and antifouling properties. The protein-based biomaterial demonstrated a safe and environmentally friendly way of antimicrobials, showing significant potential for reducing membrane fouling in membrane filtration applications.
Review
Engineering, Chemical
Huaixun Lim, Kunli Goh, Miao Tian, Rong Wang
Summary: This review compares different types of membrane processes for air dehumidification, identifies three categories of membrane-based dehumidification, and analyzes their driving force, membrane structure, and performance indicators. The study reveals that different categories of membrane materials have different adaptability and performance in the dehumidification process. Finally, the overall performance of the three categories is summarized, and potential material innovations are discussed.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Engineering, Chemical
Yuan-Teng Shi, Xiaoting Meng, Lei Yao, Miao Tian
Summary: This study demonstrates the importance of controlling residual chlorine content in front-end inlet water to maintain the long-term efficiency of nanofiltration membrane. The use of a pre-treatment unit such as coconut shell activated carbon can effectively remove residual chlorine, ensuring the efficiency and lifespan of the nanofiltration membrane. This work provides valuable insight for the development of nanofiltration membrane for large-scale separation and resource recovery of NaCl and Na2SO4 from coal chemical wastewaters.
Article
Engineering, Chemical
Xiaofei You, Jeng Yi Chong, Keng Siang Goh, Miao Tian, Jia Wei Chew, Rong Wang
Summary: Electrospun polyimide nanofiber substrates were successfully fabricated for thin-film composite (TFC) membranes in organic solvent nanofiltration (OSN) by chemical cross-linking and heat-pressing, with a polyamide thin film layer synthesized through interfacial polymerization for excellent solvent permeabilities and rejection rates.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Chemical
Mahmood Zarak, Saleem Atif, Xiaoting Meng, Miao Tian
Summary: This study demonstrates an interfacial design strategy to disperse TiO2@ZIF-8 composites into a thin-film composite (TFC) membrane, improving the polymer-filler compatibility and mass transfer coefficient, and enhancing the mechanical stability and mass transfer efficiency of the membrane.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2022)
Article
Engineering, Chemical
Miao Tian, Xiaoting Meng, Qingsong Liu, Wenlu Li, Xiaofei You, Chang Liu, John D. Fortner
Summary: The study focuses on the incorporation of 2D nanomaterials, such as Graphene-Family nanomaterials and montmorillonite, in desalination applications. The researchers systematically studied the formation and performance of polyamide membranes modified with exfoliated montmorillonite. The results showed that exfoliated montmorillonite improved the permeability and selectivity of the membranes, and also had a positive effect on their surface morphology, roughness, hydrophilicity, and chlorine resistance.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Engineering, Chemical
Shaoxiong Zhai, Zhongrui Lu, Yuna Ai, Xin Liu, Qian Wang, Jun Lin, Shaojian He, Miao Tian, Lin Chen
Summary: In this study, composite proton exchange membranes with functionalized nanoparticles were prepared to improve proton conductivity and reduce vanadium permeability. The membranes demonstrated higher proton conductivity and lower vanadium permeability, resulting in improved energy efficiency in vanadium redox flow batteries.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Engineering, Environmental
Tao Ma, Haiqing Hui, Xiaofei You, Zhiqiang Pei, Miao Tian, Bing Wu
Summary: This study developed a nanofibrous thin-film composite (TFC) forward osmosis (FO) membrane with a tiered dual-layer nanofibrous substrate to enhance membrane stability and cleaning efficiency. The dual-layer nanofibrous substrate showed improved water flux and maintained water/solute selectivity in the presence of foulants in both the feed solution and draw solution.
FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING
(2022)
Article
Engineering, Chemical
Yafeng Ren, Ruhe Lian, Zongxu Liu, Guoxian Zhang, Wenbin Wang, Dongliang Ding, Miao Tian, Qiuyu Zhang
Summary: The study develops a high-porosity composite aerogel to address the poor mechanical properties, low evaporation rates, and short service life of materials used in solar steam regeneration. The composite aerogel exhibits excellent evaporative performance and durability under 1 sun irradiation, and achieves high removal efficiency in simulated seawater distillation experiments.
Article
Engineering, Chemical
Miao Tian, Haiqing Hui, Tao Ma, Guanru Zhao, Mahmood Zarak, Xiaofei You, Wenlu Li
Summary: A nanofilm made of lysozyme can be used to tune the nanopore and surface charge of NF membranes, protecting them from oxidation and maintaining rejection rates at around 96%.
Article
Engineering, Chemical
Zarak Mahmood, Miao Tian, Robert Field
Summary: Economic development generates harmful pollutants, causing environmental damage. The extractive membrane bioreactor (EMBR) is a potential alternative technology with high removal efficiency. However, technological progress and membrane fouling remain challenges.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Fei Hao, Xinyi Li, Jiameng Wang, Ruoyue Li, Liyan Zou, Kai Wang, Fuqing Chen, Feixiong Shi, Hui Yang, Wen Wang, Miao Tian
Summary: This study proposes an efficient, economical, automated, and sustainable method for separating bioproducts from cyanobacteria culture medium. It integrates sucrose-secreting cyanobacteria production process and pressure-driven membrane filtration technology. The membrane filtration process effectively separates the produced sucrose from the cyanobacteria cultures. The method is found to be economical and sustainable as it allows continuous growth of cyanobacterial species and does not cause severe membrane surface destruction.
Review
Biochemistry & Molecular Biology
Miao Tian, Tao Ma, Kunli Goh, Zhiqiang Pei, Jeng Yi Chong, Yi-Ning Wang
Summary: Forward osmosis (FO) is a promising separation technology that can overcome the challenges of pressure-driven membrane processes. FO process has significant advantages in treating feeds with high salinity and viscosity. This review focuses on the development of FO membranes and the importance of membrane selective layers in real applications.
Article
Engineering, Chemical
Somin Lee, Hee-Jun Kim, Miao Tian, Gilson Khang, Hyun-Woo Kim, Tae-Hyun Bae, Jaewoo Lee
Summary: The study focused on preventing scaling on reverse osmosis membranes by coating silk fibroin, with the coated membrane showing advantages in anti-scaling properties.
Review
Engineering, Environmental
Zarak Mahmood, Hui Cheng, Miao Tian
Summary: Wastewater treatment is important for environmental protection, human health, resource conservation, and energy recovery. Anaerobic membrane bioreactor (AnMBR) technology has gained significant attention due to its higher efficiency, advanced membrane materials, and systematic designs. It shows great potential for addressing the worldwide energy crisis through energy demand and resource recovery from wastewater.
ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY
(2022)
