期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 121, 期 5, 页码 2567-2572出版社
WILEY-BLACKWELL
DOI: 10.1002/app.33980
关键词
azo polymer; optics; thermo-optic coefficient; transmission loss
资金
- Natural Science of Jiangsu Province [BK2008247]
- China Postdoctoral Science Foundation [20070420973]
A novel chiral azobenzene polyurethane (CAPU) was prepared from chromophore, chiral reagent L(-)-tartaric acid and toluene diisocyanate (TDI). The chemical structure and the thermal property were characterized by UV-Vis spectrum, FT-IR, (1)H NMR, circular dichroism (CD) spectrum, differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). DSC and TGA experiments showed that the glass transition temperature (T(g)) and the decomposition temperature (T(d)) at 5% mass loss were 110 degrees C and 199 degrees C, respectively. The refractive index (n) and thermo-optic coefficient (dn/dT) of the CAPU were measured at 650 nm wavelength and different temperature by attenuated total reflection (ATR) technique. By using CCD digital imaging devices, transmission loss of CAPU was measured and the value is 0.565dB/cm. The results will provide the foundation for many potential applications such as digital thermo-optic switch materials and other fields in the future. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 121: 2567-2572, 2011
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