期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 117, 期 2, 页码 793-800出版社
WILEY
DOI: 10.1002/app.31078
关键词
conducting polymers; electrochemistry
资金
- Natural Science Foundation of Shandong Province [Y2007B22]
- Scientific and Technical Development Project of Qingdao [07-2-3-11-jch]
- National Natural Science Foundation of China [20775038, 50663001]
High-quality poly(9,10-dihydrophenanthrene) (PPh) with good fluorescence properties was synthesized electrochemically by the direct anodic oxidation of 9,10-dihydrophenanthrene in boron trifluoride diethyl etherate (BFEE). PPh films obtained from BFEE-based electrolytes showed good electrochemical behavior and good thermal stability with an electrical conductivity of 2.2 x 10(-3) S/cm; this indicated that BFEE was a better medium for the electrosyntheses of PPh films. Dedoped PPh films were soluble in CH2Cl2, dimethylformamide, and dimethyl sulfoxide. The structure and morphology of the polymer were also characterized by ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, H-1-NMR spectroscopy, and scanning electron microscopy, respectively, which indicated the polymerization mainly occurred at the C-(2) and C-(7) positions. Fluorescent spectral studies indicated that PPh was a good blue-light emitter. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 793-800, 2010
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