4.6 Article

Preparation and Investigation of Ethylene-Vinyl Acetate Copolymer/Silicone Rubber/Clay Nanocomposites

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JOURNAL OF APPLIED POLYMER SCIENCE
卷 113, 期 3, 页码 1664-1670

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WILEY
DOI: 10.1002/app.30288

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clay; flame retardance; nanocomposites; polyolefins; silicones

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In this article, the combination of silicone rubber (SR) elastomer with synthetic iron montmorillonite (Fe-MMT) to form a kind of new flame-retardant system based on an ethylene-vinyl acetate (EVA) copolymer is first reported. Also, the flame retardancy of the EVA/SR/Fe-MMT hybrid are compared with that of EVA/SR/natural sodium montmorillonite. The structures of the nano-composites were characterized with X-ray diffraction and transmission electron microscopy. Cone calorimeter tests and thermogravimetric analysis were used to evaluate the flame-retardant properties and thermal stability of the composites, respectively. In addition, tensile tests were carried Out with a universal testing machine, and the morphology of the fracture surface was observed with environmental scanning electron microscopy. We found that SR/organophilic montmorillonite (Fe-OMT) was more effective in reducing the primary peak heat release rate of the nanocomposite, and the EVA/SR/Fe-OMT hybrid had a higher thermal stability in the deacetylated polymer than EVA/SR/sodium organophilic montmorillonite. Moreover, the exfoliated EVA/SR/Fe-OMT nanocomposite displayed excellent mechanical properties because of a better dispersion of Fe-OMT in the polymer matrix, and a possible mechanism is discussed. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 113: 1664-1670, 2009

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