Grafted CMC/silica gel superabsorbent composite: Synthesis and investigation of swelling behavior in various media

In the present study, we attempt to synthesize and characterize novel CMC-g-poly (acrylic acid-co-2-acrylamido-2-methylpropane sulfonic acid)/silica gel composite. Infrared spectroscopy and TGA thermal analysis were carried out to confirm the chemical structure of the hydrogel. Moreover, morphology of the samples was examined by scanning electron microscopy. The effect of reaction variables affecting on water absorbency of the composite and swelling behavior in various solvents, salt, and pH solutions was investigated. Maximum water absorbency of the optimized final product was found to be 4000 g/g in distilled water. The absorbency under load (AUL) of the hydrogel was also determined by using an AUL tester at various applied pressures. Finally, dynamic swelling kinetics of the hydrogel was studied. (C) 2008 Wiley Periodicals, Inc.