期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 108, 期 5, 页码 2975-2982出版社
WILEY
DOI: 10.1002/app.27925
关键词
biocompatibility; biodegradable; FT-IR; polycondensation; thermogravimetric analysis (TGA)
A new class of optically active poly(amide imide urethane)s (PAIUs) was synthesized via a two-step dlisocyanate route. In the first step, 4,4-methylenebis(phenyl isocyanate) (MDT) was reacted with different diacids to produce an isocyanate-terminated oligo(amide imide). The chain extension of the previous hard segment with poly (ethylene glycol) diols with a molecular weight of 400 was the second step for furnishing a series of new PAIUs. N-Trimellitylimido-L-leucine was used as a diacid monomer for polycondensation reactions. Polymerization reactions were performed without any catalysts or with pyridine or dibutyltin dilaurate as a catalyst. The optimized reaction conditions were used for the reaction of N-trimellitylimido-L-isoleucine, N-trimellitylimido-L-methionine, N-trimellitylimidos-valine, and N-trimellitylimido-L-phenylalanine as diacid monomers with MDI. The resulting multiblock copolymers had inherent viscosities of 0.25-0.78 dL/g. These multiblock copolymers were optically active, thermally stable, and soluble in an-tide-type solvents. All these polymers were fully characterized with Fourier transform infrared spectroscopy, H-1-NMR and ultraviolet-visible spectroscopy, specific rotation measurements, and thermal analyses. Some structural characteristics and physical properties of these new optically active PAIUs were examined. (C) 2008 Wiley Periodicals, Inc.
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