Article
Materials Science, Multidisciplinary
Suyue Yuan, Aoyan Liang, Chang Liu, Aiichiro Nakano, Ken-ichi Nomura, Paulo S. Branicio
Summary: We uncover a vacancy-like structural motif named Q7 in metallic glasses, which plays a significant role in short-range structural disorder and is correlated with the thermal and mechanical behavior of metallic glasses. The discovery of the Q7 motif provides new insights into understanding the relationship between local disorder and structural relaxation in metallic glasses.
MATERIALS & DESIGN
(2023)
Article
Nanoscience & Nanotechnology
X. Yuan, D. Sopu, F. Spieckermann, K. K. Song, S. Ketov, K. G. Prashanth, J. Eckert
Summary: Rejuvenation is the reverse process of relaxation in metallic glasses, which increases their free volume and brings them to a higher energy state. This study explores the controllable rejuvenation degree through a dilution procedure and identifies the maximum rejuvenation threshold. The activation of structural relaxation and the dynamic balance between free volume creation and annihilation determine the rejuvenation ability of metallic glasses. The highest degree of rejuvenation is related to the flow strain of the materials and exhibits a structure similar to shear bands.
SCRIPTA MATERIALIA
(2022)
Article
Multidisciplinary Sciences
Nicolas Amigo, Simon Palominos, Felipe J. Valencia
Summary: This study employed machine learning models to predict the plastic properties in CuZr metallic glasses. Molecular dynamics simulations were conducted for 100 different samples, and statistical analysis was performed on 17 materials properties. Strong correlations were found between stoichiometry, temperature, structural, and elastic properties with plastic properties. Three regression models were used for prediction, and linear and Ridge regressions showed better performance with coefficients of determination above 80% for three plastic properties. Lasso regression had lower performance with coefficients of determination above 60% for two plastic properties. Overall, this work demonstrates that molecular dynamics simulations combined with machine learning models can provide a framework for predicting the plastic behavior of complex materials.
SCIENTIFIC REPORTS
(2023)
Article
Engineering, Civil
Yu Chen, Jia-Cheng Zhang, Paulo S. Branicio, Zhen-Dong Sha
Summary: This study uses molecular dynamics simulations to investigate the mechanical properties and failure mechanisms of brick-and-mortar metallic glasses. The results show that a desirable balance between strength and plasticity can be achieved in BMMGs with appropriate brick aspect ratios and interlayer thicknesses.
THIN-WALLED STRUCTURES
(2023)
Article
Chemistry, Physical
Jiacheng Zhang, Pengfei Gao, Weixu Zhang
Summary: In this study, molecular dynamics simulations were used to investigate the effects of hydrogen doping on the atomic structure, mechanical properties, and relaxation behavior of H-doped Ni50Al50 metallic glasses. The properties of H-doped MGs were found to depend not only on the hydrogen content but also on the doping method. Doping H atoms into the molten state resulted in loose atomic structures, homogeneous deformation, and enhanced beta relaxation. On the other hand, doping H atoms into as-cast MGs affected the atomic structure and mechanical properties. A small number of H atoms had little impact on the elastic matrix, while a large number of H atoms caused a decrease in strength and a shift from shear band to homogeneous deformation.
Article
Nanoscience & Nanotechnology
Chang Liu, Zhen Zhang, Jun Ding, En Ma
Summary: Reverse Monte Carlo (RMC) simulations are widely used for generating three-dimensional models of amorphous materials. This study evaluates the reliability of RMC modeling for metallic glasses by comparing it with molecular dynamics simulations. The results show that RMC-generated structures lack accuracy in reproducing the local atomic packing, and additional constraints and validation check points are advised for obtaining a physically stable and meaningful atomic configuration.
SCRIPTA MATERIALIA
(2023)
Article
Chemistry, Physical
Shuang Ma, Yuzhu Ran, Xinyu Liang, Li Jiang, Yanhui Li, Xudong Wang, Man Yao, Wei Zhang
Summary: The effects of Y content on the glass-forming ability and soft magnetic properties of Co-based metallic glasses were investigated. The addition of Y improved the glass-forming ability and magnetic softness, but excessive Y content led to a reduction in these properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Xiaoqian Lu, Shidong Feng, Lin Li, Li-Min Wang, Riping Liu
Summary: This study tackles the challenge of identifying defects in metallic glasses by using atomic vibrational entropy from a thermodynamic perspective. The study reveals the critical role of vibrational entropy in bridging dynamics, thermodynamics, and structure in metallic glasses. The local vibrational entropy obtained by coarse-graining the atomic vibrational entropy in space effectively distinguishes between liquid-like and solid-like atoms and establishes a correlation with the structure of metallic glasses, offering a route to predict plastic events.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Syamal Praneeth Chilakalapudi, Shyam Katnagallu, Abhishek Sarkar, Penghui Cao, Wolfgang Wenzel, Horst Hahn
Summary: Metallic glasses prepared by cluster assembly method exhibit different atomic structures with higher local order compared to those quenched rapidly. Two distinct amorphous phases are identified in the cores of clusters and continuous network of interfaces. The results show that the short- and medium-range orders of cluster-assembled glasses can be tailored by varying the deposition energy.
Article
Materials Science, Multidisciplinary
K. K. Qiu, X. D. Wang, T. D. Xu, Q. . P. Cao, S. Q. Ding, D. X. Zhang, K. A. Beyer, J. Z. Jiang
Summary: The memory effect in metallic glasses is observed through differential scanning calorimetry and molecular dynamics simulations, indicating that it may originate from the structural rejuvenation and formation of more loose packing configurations during high temperature annealing. In contrast, the high-low temperature annealing only induces monotonic relaxation.
MATERIALS TODAY PHYSICS
(2022)
Article
Materials Science, Ceramics
Feng Li, Jingqi Zhang, Xinyu Xu, Hui Wang, Liang Feng, Hui Chang
Summary: In this study, molecular dynamics simulations were used to explain the splitting of the second peak in the pair distribution function (PDF) of Cu monatomic metallic glass (MG). The atomic packing in Cu MG exhibits a combination of spherical-periodic order and local translational symmetry. Voronoi tessellation analyses reveal that the dominant cluster is a crystal-like polyhedron <0, 3, 6, 4>. The splitting of the second peak is caused by the diverse connections between atomic clusters, with the first sub-peak originating from face-sharing clusters and the second sub-peak resulting from the alignment of central atoms and sharing atoms of vertex-sharing clusters.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2023)
Article
Engineering, Mechanical
A. Khmich, A. Hassani, K. Sbiaai, A. Hasnaoui
Summary: Metallic glasses exhibit high mechanical performance but are usually brittle. Reinforcement of the metallic glass matrix to form composite materials is necessary for improved ductility and toughness. Molecular dynamics simulations can provide insights into the effects of adding Ta and W monocrystalline fibers on the mechanical properties of metallic glasses.
INTERNATIONAL JOURNAL OF MECHANICAL SCIENCES
(2021)
Article
Multidisciplinary Sciences
Angelo Lucia, Otto Gregory
Summary: Metal oxide glasses are crucial in various industries due to their adjustable properties. However, there is a lack of accurate and efficient modeling tools to predict their thermomechanical properties. This article introduces a novel multi-scale modeling framework based on Monte Carlo simulation and cubic equation of state. The framework characterizes the glass transition and softening temperatures and incorporates a new moving boundary equation of state that considers structure and 'soft' repulsion. The modeling capabilities are demonstrated through comparison with experimental data. Additionally, this work provides a rigorous approach to estimate thermophysical properties for guiding experimental work.
SCIENTIFIC REPORTS
(2023)
Article
Nanoscience & Nanotechnology
Chang Liu, Suyue Yuan, Paulo S. Branicio
Summary: Bicontinuous nanoporous metallic glasses combine the advantages of MGs and open-cell nanoporous materials. Molecular dynamics simulations of a bicontinuous nanoporous Cu64Zr36 MG with 55% porosity and 4.4 nm ligament size show anomalous mechanical behavior and the ability to effectively delocalize strain localization in MGs. This design may have potential applications in catalysis, sensors, and lightweight structural designs.
SCRIPTA MATERIALIA
(2021)
Article
Chemistry, Physical
Xudong Yuan, Daniel Sopu, Kaikai Song, Juergen Eckert
Summary: Increasing free volume in metallic glasses rejuvenates them, but this free volume can be annihilated under deformation leading to structural relaxation and strain-hardening. Highly rejuvenated metallic glasses experience stress-driven structural and residual stress relaxation during cycling deformation, eventually reaching a more stable state but unable to recover their initial state.
Article
Materials Science, Multidisciplinary
Rathinavelu Sokkalingam, Zhao Chao, Katakam Sivaprasad, Veerappan Muthupandi, Jayamani Jayaraj, Parthiban Ramasamy, Juergen Eckert, Konda Gokuldoss Prashanth
Summary: CoCrFeMnNi high-entropy alloy/AISI 316L stainless steel bimetal was fabricated using SLM, showing enhanced hardness and tensile strength due to the composition and structure advantages. However, the presence of defects and higher susceptibility to pitting corrosion in CoCrFeMnNi-HEA make it more prone to corrosion attack in corrosive environments.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Sepide Hadibeik, Florian Spieckermann, Martin Nosko, Farzad Khodabakhshi, Mahmoud Heydarzadeh Sohi, Juergen Eckert
Summary: A novel approach for fabricating bulk metallic glass using additive manufacturing has been studied, however, there are challenges, such as unmelted powder and compositional deviation, that need further investigation to optimize the process parameters.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Jelena Petrusa, Benjamin Meier, Gerda Gruenbacher, Wolfgang Waldhauser, Juergen Eckert
Summary: The effects of laser energy density on the relative density and microstructure of cp-TiGd2 fabricated by LB-PBF were studied, and the influence of printing orientation and different surface treatments on surface topography and biocompatibility were investigated. The aim is to develop additive manufacturing process parameters that can achieve full density and satisfactory biocompatibility for cp-TiGd2 as a low-cost alternative to biomedical materials. An optimized process with high density, improved surface roughness, and noncytotoxicity was achieved using a wide range of process parameters.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Chemistry, Physical
Zequn Zhang, Simon Fellner, Sergey Ketov, Megan J. Cordill, Huaping Sheng, Christian Mitterer, Kaikai Song, Christoph Gammer, Juergen Eckert
Summary: The phase evolution of alloys and atomic diffusion are closely related. However, the influence of reactive diffusion on phase formation in high-entropy alloys (HEAs) is still not clear. This study investigates the phase evolution of a multicomponent CoCrFeNi/Al diffusion couple and reveals the combined effects of enthalpy and entropy on phase formation in HEAs at elevated temperatures. Surface modification of HEAs can be achieved through film deposition and annealing processes.
Review
Electrochemistry
Baran Sarac, A. Sezai Sarac, Juergen Eckert
Summary: This review provides an introduction to the use of advanced amorphous metal catalysts for hydrogen storage and production via electrochemistry. Pd-based metallic glasses have gained significant attention due to their unique atomic structure and properties for energy applications. The review covers the fabrication techniques, hydrogen sorption, hydrogen evolution, kinetics, and future prospects of Pd-based metallic glasses. Overall, it offers a comprehensive overview for large-scale hydrogen energy storage and production systems.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Ming-Zhi Zhang, Kun Zhang, Kai-Kai Song, Xiao-Yu Zou, Wei-Dong Song, Ke-Feng Li, Li-Na Hu, Ze-Qun Zhang, Juergen Eckert
Summary: In this study, CoCrFeMnNi high-entropy alloys with a surface gradient nanostructure were produced using industrial shot blasting, which significantly improved their mechanical properties. The severely plastically deformed surface layer had a multi-scale hierarchical structure and increased in depth with shot-blasting time. The microhardness and tensile strength of the alloy were significantly higher after shot-blasting. The improved strain hardening and prevention of early necking in the gradient-nanostructured surface layer contributed to its high toughness.
Article
Chemistry, Physical
Monika Antoni, Florian Spieckermann, Niklas Plutta, Christoph Gammer, Marlene Kapp, Parthiban Ramasamy, Christian Polak, Reinhard Pippan, Michael J. J. Zehetbauer, Juergen Eckert
Summary: The effects of severe plastic deformation (SPD) by means of high-pressure torsion (HPT) on Fe73.9Cu1Nb3Si15.5B6.6 and Fe81.2Co4Si0.5B9.5P4Cu0.8 iron-based metallic glasses were compared. HPT processing extended the consolidation and deformation ranges for Fe73.9Cu1Nb3Si15.5B6.6, and achieved consolidation and deformation with minimum cracks for Fe81.2Co4Si0.5B9.5P4Cu0.8 for the first time. Various analyses revealed that Fe81.2Co4Si0.5B9.5P4Cu0.8 exhibited HPT-induced crystallization phenomena, while Fe73.9Cu1Nb3Si15.5B6.6 did not crystallize even at high HPT-deformation degrees.
Editorial Material
Chemistry, Multidisciplinary
Juergen Eckert, Daniel Kiener
Article
Chemistry, Physical
Keziban Huner, Baran Sarac, Eray Yuece, Amir Rezvan, Matej Micusik, Maria Omastova, Juergen Eckert, A. Sezai Sarac
Summary: The incorporation of iron and carboxylic acid-functionalized polyaniline into polymeric polycaprolactone structures enhances the electron-donating ability and conductivity of the compound, making it suitable for electrochemical immunosensors.
MOLECULAR SYSTEMS DESIGN & ENGINEERING
(2023)
Article
Engineering, Mechanical
Bin Chen, Yunli Li, Daniel Sopu, Juergen Eckert, Wenping Wu
Summary: The shock-induced dynamic mechanical behavior and spallation failure of Ni-based single crystal superalloys are studied using non-equilibrium molecular dynamic simulations. Two modes of classical spallation and micro-spallation are observed during the spallation failure. The deformation mechanism is dominated by slip and drag of dislocations at low shock velocities, while complex phase transitions from FCC to BCC or disordered structures occur at higher velocities, leading to a decrease in spallation strength. The presence of voids significantly lowers the spallation strength, and the reduction in strength is proportional to the radius of the voids.
INTERNATIONAL JOURNAL OF PLASTICITY
(2023)
Article
Materials Science, Multidisciplinary
Xiaoming Liu, Zongde Kou, Ruitao Qu, Weidong Song, Yijia Gu, Changshan Zhou, Qingwei Gao, Jiyao Zhang, Chongde Cao, Kaikai Song, Vladislav Zadorozhnyy, Zequn Zhang, Juergen Eckert
Summary: This study utilizes high-temperature extrusion and annealing to optimize the microstructures and mechanical properties of the Co34Cr32Ni27Al3.5Ti3.5 multicomponent alloy. Hot extrusion reduces grain sizes and promotes the precipitation of nanoparticles inside the FCC matrix and grain boundaries. Subsequent annealing regulates the microstructures and enhances the mechanical properties.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Ming-Wei Wu, Kai Ni, Yang Lei, Xin-Xing Xiong, Yi-Ting Chuang, Quiao-En Lin, Pei Wang, Parthiban Ramasamy, Juergen Eckert
Summary: Selective laser melting (SLM) was utilized to produce CuZrAl metallic glass (MG) scaffolds with combined lattice structures of body-centered cubic and face-centered cubic (F2BCC), and the effects of lattice structures on mechanical behavior were investigated. The results revealed that curved struts remarkably enhanced compressive ductility by 122% and energy absorption by 106%. The presence of curved struts effectively prevented catastrophic shear fracture and delayed fracture occurrence due to the release of strain concentrations. This study demonstrates the potential of improving the ductility and toughness of SLM MG components through appropriate lattice structure design.
Article
Engineering, Manufacturing
Ruiqi Wang, Lixia Xi, Lili Feng, Baran Sarac, Konda Gokuldoss Prashanth, Juergen Eckert, Dongdong Gu
Summary: Dual-phase reinforcing approach is an efficient strategy for fabricating advanced aluminum matrix composites. However, designing a dual-phase reinforcing system with synergistic strengthening effect for LPBF process is challenging.
3D PRINTING AND ADDITIVE MANUFACTURING
(2023)
Article
Materials Science, Multidisciplinary
Xintian Wang, Zhiyong Ji, Robert O. Ritchie, Ilya Okulov, Juergen Eckert, Chunlei Qiu
Summary: In this study, TiAl and Cr3C2 particles were added to a CrMnFeCoNi alloy to improve its processibility and mechanical properties. The addition of TiAl particles resulted in the formation of cracks, but the further addition of Cr3C2 particles helped suppress hot cracking. The presence of long-range ordered domains and precipitates contributed to the improved strength of the dual-particle containing alloy.
MATERIALS TODAY ADVANCES
(2023)
Article
Chemistry, Physical
Baran Sarac, Remzi Gurbuz, Matej Micusik, Maria Omastova, Amir Rezvan, Eray Yuece, Lixia Xi, Juergen Eckert, Ali Ozcan, A. Sezai Sarac
Summary: This study focuses on the synthesis and properties comparison of a novel organic composite nanofiber material consisting of styrene-butadiene-styrene (SBS) copolymer blended with polystyrene (PStyr) and carbon nanotubes (CNTs). The addition of CNTs retards the crystallization process and decreases the absorbance of both SBS/PStyr and PStyr/PBu in Fourier transform infrared spectroscopy. The interaction of CNTs with the blend is limited in samples with SBS, as observed in Raman spectroscopy.
MOLECULAR SYSTEMS DESIGN & ENGINEERING
(2023)