期刊
JOURNAL OF APPLIED PHYSICS
卷 107, 期 4, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3284088
关键词
antimony alloys; barium alloys; calcium alloys; cobalt alloys; Debye temperature; electrical resistivity; lattice constants; nanostructured materials; nickel alloys; platinum alloys; specific heat; strontium alloys; thermal expansion; tin alloys; X-ray analysis; ytterbium alloys
资金
- Austrian FWF [P19284-N20, S10406N16]
- OEAD [PL-06/2009]
The current paper gives an overview of the newly obtained thermal expansion coefficients of skutterudites as well as those so far available in literature. Thermal expansion was determined for CoSb3, Pt4Sn4.4Sb7.6, for As- and Ge-based skutterudites as well as for various high-ZT skutterudites (micro- and nanostructured) with didymium (DD) and mischmetal (Mm) as filler atoms in frameworks of (Fe1-xCox)(4)Sb-12 and (Fe1-xNix)(4)Sb-12, and for double and triple-filled skutterudites such as Ca0.07Ba0.23Co3.95Ni0.05Sb12 and Sr0.025Ba0.075Yb0.1Co4Sb12. For low temperatures, a capacitance dilatometer was used (4-300 K), whereas for temperatures 300 < T < 750 K, a dynamic mechanical analyzer was employed. For a set of Ge-, P-, and Sb-based skutterudites, lattice parameters of single crystals, measured at three different temperatures, were used to derive the thermal expansion coefficient. The semiclassical model of Mukherjee [Phys. Rev. Lett. 76, 1876 (1996)] has been successfully used to quantitatively describe the thermal expansion coefficient in terms of Einstein and Debye temperatures, which compare well with the corresponding results from specific heat, electrical resistivity, or temperature dependent x-ray measurements.
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