4.6 Article

Enhanced multiferroic characteristics in NaNbO3-modified BiFeO3 ceramics

期刊

JOURNAL OF APPLIED PHYSICS
卷 105, 期 5, 页码 -

出版社

AMER INST PHYSICS
DOI: 10.1063/1.3081648

关键词

antiferromagnetism; bismuth compounds; crystal structure; dielectric hysteresis; dielectric relaxation; ferroelectric ceramics; ferroelectric coercive field; ferromagnetic materials; high-temperature effects; magnetisation; multiferroics; sodium compounds; solid solutions

资金

  1. Natural Science Foundation of China [50832005, 50672083]
  2. National Basic Research Program [2009 CB623302]

向作者/读者索取更多资源

Modification of BiFeO3 multiferroic ceramics were investigated by introducing NaNbO3 to form (Bi1-xNax)(Fe1-xNbx)O-3 (x=0.1, 0.3, and 0.5) solid solutions. With increasing NaNbO3 content, the crystalline structure changed and the ferroelectric properties were improved. The significantly reduced leakage resulted in more regular ferroelectric hysteresis loop for all compositions. Dielectric characteristics of (Bi1-xNax)(Fe1-xNbx)O-3 (x=0.1, 0.3, and 0.5) ceramics were evaluated. Two dielectric relaxations were observed in the temperature ranges of 550-600 and 650-710 K in (Bi0.9Na0.1)(Fe0.9Nb0.1)O-3 ceramics, and the higher-temperature dielectric relaxation was related to the antiferromagnetism transition, which indicated the coupling between the ferroelectric and magnetic orders essential for the multiferroic materials. Moreover, weak ferromagnetism with remnant magnetization (M-r) of 0.14 emu/g and coercive field (H-c) of 6.48 kOe were observed in the sample with x=0.1, which suggested that the present modified ceramics had enhanced multiferroic characteristics.

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