期刊
JOURNAL OF APPLIED ELECTROCHEMISTRY
卷 43, 期 5, 页码 497-505出版社
SPRINGER
DOI: 10.1007/s10800-013-0532-7
关键词
Lithium-ion batteries; Electrolytes; Low temperature performance
资金
- Office of Vehicle Technologies of the U.S. Department of Energy under Batteries for Advanced Transportation Technologies (BATT) Program [DE-AC02-05CH11231, 6879235]
Methyl butyrate (MB) has been investigated as a co-solvent for lithium-ion battery electrolytes to improve the performance at low temperature (-10 to -30 A degrees C). The cycling performance of graphite/LiNi1/3Co1/3Mn1/3O2 cells with 1.2 M lithium tetrafluorooxalatophosphate (LiFOP) in 2:2:6 EC/EMC/MB was compared to 1.2 M LiPF6 in both 3:7 EC/EMC and 2:2:6 EC/EMC/MB. The LiFOP/MB electrolyte has a good operational temperature window and comparable cycling performance to the LiPF6 electrolyte at both room temperature and low temperature (-10 A degrees C). However, after accelerated aging the LiFOP/MB electrolyte has worse performance at very low temperature (-30 A degrees C) compared to LiPF6 electrolytes. Ex-situ surface analysis was conducted by scanning electron microscopy, X-ray photoelectron spectroscopy, and Fourier transfer infrared spectroscopy to provide insight into the performance differences.
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