期刊
JOURNAL OF APPLIED ELECTROCHEMISTRY
卷 39, 期 7, 页码 1105-1110出版社
SPRINGER
DOI: 10.1007/s10800-008-9765-2
关键词
Lithium-ion battery; Graphite; Thermal behavior; C80 micro-calorimeter; 4-Isopropyl phenyl diphenyl phosphate
资金
- National Science Foundation of China [20603034]
To enhance the thermal stability of graphite electrodes for lithium-ion batteries, 4-isopropyl phenyl diphenyl phosphate (IPPP) was investigated as an additive in the electrolyte of 1.0 M LiPF6 in ethylene carbonate and diethyl carbonate (1: 1 in weight). The electrochemical performance of Li/IPPP-electrolyte/C half cells was evaluated. The thermal behavior of LixC6 and LixC6-IPPP-electrolytes were examined using a C80 micro-calorimeter. Electrolytes with 5 and 10% IPPP improve the thermal stability of the graphite electrode in the tests. The electrochemical performance of Li/IPPP-electrolyte/C cells is not degraded by the addition of this amount of IPPP to the electrolyte.
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