4.6 Article

Activated carbon derived from waste coffee grounds for stable methane storage

期刊

NANOTECHNOLOGY
卷 26, 期 38, 页码 -

出版社

IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/26/38/385602

关键词

adsorption; activated carbon; methane storage; energy storage; mechanism; hydrogen storage

资金

  1. NRF [2010-0020414]
  2. National Research Foundation of Korea [2010-0020414] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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An activated carbon material derived from waste coffee grounds is shown to be an effective and stable medium for methane storage. The sample activated at 900 degrees C displays a surface area of 1040.3 m(2) g(-1) and a micropore volume of 0.574 cm(3) g(-1) and exhibits a stable CH4 adsorption capacity of similar to 4.2 mmol g(-1) at 3.0 MPa and a temperature range of 298 +/- 10 K. The same material exhibits an impressive hydrogen storage capacity of 1.75 wt% as well at 77 K and 100 kPa. Here, we also propose a mechanism for the formation of activated carbon from spent coffee grounds. At low temperatures, the material has two distinct types with low and high surface areas; however, activation at elevated temperatures drives off the low surface area carbon, leaving behind the porous high surface area activated carbon.

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