Production and characterization of microporous activated carbons and metallurgical bio-coke from waste shell biomass

To produce activated carbon and bio-coke, palm kernel shells (PKS), walnut shells (WNS) and cashew nut shells (CNS) were carbonized and (or) activated. The activation was conducted using CO2 in a fixed bed reactor. In the activation of PKS, the influence of CO2 flow rate on the surface area development was also examined. Meanwhile, to evaluate the suitability of chars obtained from CNS as metallurgical bio-coke, carbonization was carried out in N-2 at temperatures of 700-800 degrees C. The maximum surface areas of the resultant activated carbons derived from each biomass were about 700-810 m(2)/g, and all the activated carbons had a microporous nature. At a CO2 flow rate of 1 NL/min, the activated carbon obtained from PKS showed the highest surface area of 912 m(2)/g. The char produced from CNS, with its low ash and volatile matter contents and its sufficient compressive strength, demonstrated promising potential as metallurgical bio-coke. (C) 2014 Elsevier B.V. All rights reserved.