期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 536, 期 -, 页码 S477-S479出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2011.11.057
关键词
Amorphous materials; Nanostructured materials; Crystal growth; Synchrotron radiation
资金
- Marie Curie EU-FP6 Mineral Nucleation and Growth Kinetics (MIN-GRO) Research and Training Network [MRTNCT-2006-035488]
- CCLRC [50115, 50218]
- Diamond Light Source [SM4595, SM1132]
The effects of pH and Mg on the crystallization of amorphous calcium carbonate (ACC) to vaterite and/or calcite were studied using a combination of in situ time resolved synchrotron-based techniques and electron microscopy. The experiments showed that Mg increased the stability of ACC and favoured the formation of calcite over vaterite. A neutral (similar to 7) starting pH during mixing promoted the transformation of ACC into calcite via a dissolution/reprecipitation mechanism. Conversely, when ACC formed in a solution that started with a high initial pH (similar to 11.5), the transformation to calcite occurred via metastable vaterite, which formed via a spherulitic growth mechanism. In a second stage this vaterite transformed to calcite via a surface-controlled dissolution and recrystallization mechanism. These crystallization pathways can be explained as a consequence of the pH-dependent composition, local structure, stability and dissolution rates of ACC. (c) 2011 Elsevier B.V. All rights reserved.
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