4.7 Article

Improvement of rate capability of spinel lithium titanate anodes using microwave-assisted zinc nanocoating

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 513, 期 -, 页码 393-398

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2011.10.055

关键词

Li4Ti5O12; Li-ion battery; Microwave deposition; Zinc coating; Anode materials

资金

  1. National Science Council of the Republic of China [NSC 99-2632-E-155-001-MY3]

向作者/读者索取更多资源

In this study, the deposition of microwave-assisted Zn layers onto spinel lithium titanate (Li4Ti5O12) crystals as superior anode materials for Li-ion batteries has been investigated. Microwave heating is capable of rapidly depositing Zn layers over the surface of spinel Li4Ti5O12 within 6 min. The thickness of Zn layer (i.e., 1-10 nm) is an increasing function of zinc nitrate concentration under the microwave irradiation. The charge-discharge curve of Zn-Li4Ti5O12 anode still maintains the plateau at 1.5 V, contributing to the major portion in the overall specific capacity. The presence of Zn coating significantly facilitates the capacity retention (78.1% at 10 C/0.2 C) of the composite anodes with high Coulombic efficiency (>99.9%), indicating an excellent reversibility of insertion/de-insertion of Li ions. This can be ascribed to the fact that well-dispersed Zn layer offers an electronic pathway over the Li4Ti5O12 powder, thus imparting electronic conduction and reducing cell polarization. Accordingly, the deposition of Zn coating, prepared by the rapid microwave heating, shows a positive effect on the rate-capability improvement of Li4Ti5O12 anodes. (C) 2011 Elsevier B. V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Engineering, Chemical

Revisiting temperature effect on the kinetics of liquid-phase adsorption by the Elovich equation: A simple tool for checking data reliability

Ru-Ling Tseng, Hai Nguyen Tran, Ruey-Shin Juang

Summary: Temperature has a significant effect on adsorption processes, particularly on adsorption equilibrium. While the effect of temperature on adsorption kinetics has been less explored, likely due to a lack of a simple and suitable kinetic model. This study analyzed kinetic data using the Elovich equation and found that most adsorption processes had an activation energy in the range of 12.1 to 25.6 kJ mol(-1).

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2022)

Article Biochemistry & Molecular Biology

Fouling Analysis in One-Stage Ultrafiltration of Precipitation-Treated Bacillus subtilis Fermentation Liquors for Biosurfactant Recovery

Mai Lien Tran, Ying-Shr Chen, Ruey-Shin Juang

Summary: This study investigated the primary recovery of surfactin from precipitation-pretreated fermentation broths using one-stage dead-end and cross-flow ultrafiltration. The results showed that the use of a polyethersulfone membrane and addition of ethanol were effective in recovering surfactin under suitable conditions. The Hermia model was used to understand membrane fouling mechanisms, and appropriate cleaning agents and methods were selected to restore membrane flux.

MEMBRANES (2022)

Article Chemistry, Physical

Employing functionalized graphene quantum dots to combat coronavirus and enterovirus

Chien-Te Hsieh, Siyong Gu, Yasser Ashraf Gandomi, Chun-Chieh Fu, Po-Yu Sung, Ruey-Shin Juang, Cheng-Cheung Chen

Summary: This study aims to design and synthesize antiviral nanomaterials to inhibit the development of the coronavirus through interaction with the virus. The materials prepared in this study demonstrated superior performance in virus inhibition, as shown through unique preparation techniques and biocompatibility testing. Additionally, the addition of specific substances enhanced the adsorption and inhibition of the materials on the virus surface.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Editorial Material Environmental Sciences

How to avoid mistakes in treating adsorption isotherm data (liquid and solid phases): Some comments about correctly using Radke-Prausnitz nonlinear model and Langmuir equilibrium constant

Hai Nguyen Tran, Jean-Claude Bollinger, Eder C. Lima, Ruey-Shin Juang

Summary: Two flaws in concepts related to the Radke-Prausnitz model and the Langmuir constant unit were identified and corrected in the paper. The nonlinear form of the Radke-Prausnitz model and the misconception about the unit of the Langmuir constant were thoroughly discussed to avoid unexpected mistakes in adsorption studies.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2023)

Article Engineering, Chemical

Graphene oxide crosslinked chitosan composites for enhanced adsorption of cationic dye from aqueous solutions

Mai Lien Tran, Thi Tuong Van Tran, Ruey-Shin Juang, Chi Hieu Nguyen

Summary: In this study, chitosan (CS) and graphene oxide (GO) were combined to synthesize CS/GO composites with different GO contents. The combination of CS and GO not only improved the surface area by reducing agglomeration of GO sheets, but also significantly enhanced the adsorption capacity of cationic dye on CS. The Langmuir adsorption capacity of methylene blue (MB) reached 259.5 mg/g at pH 8 and 30 degrees C for the CS/GO12 material. The composite showed good adsorption-regeneration performance.

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2023)

Article Green & Sustainable Science & Technology

Reclamation and reuse of wastewater by membrane-based processes in a typical midstream petrochemical factory: a techno-economic analysis

Cheng-Wei Lin, Hai Nguyen Tran, Ruey-Shin Juang

Summary: This study investigated the techno-economic analysis for wastewater reclamation in a midstream petrochemical factory in Taiwan. Caprolactam is the main product of this factory. Different treatment methods involving membrane-based processes were proposed to reclaim and recycle wastewater for cooling water replenishment. The economic analysis showed that the combination of ultrafiltration and reverse osmosis (Scheme 3) was the best choice.

ENVIRONMENT DEVELOPMENT AND SUSTAINABILITY (2023)

Article Nanoscience & Nanotechnology

PEDOT:PSS-Based Bioelectrodes for Multifunctional Drug Release and Electric Cell-Substrate Impedance Sensing

Yu-Sheng Hsiao, Edgar Daniel Quinones, Shih-Chieh Yen, Jiashing Yu, Ji-Tseng Fang, Peilin Chen, Ruey-Shin Juang

Summary: Electric cell-substrate impedance sensing (ECIS) is an innovative approach for the label-free and real-time detection of cell morphology, growth, and apoptosis. In this study, poly(3,4-ethylenedioxythiophene)-poly-(styrenesulfonate) (PEDOT:PSS) conducting polymer (CP)-based bioelectrodes were developed for the simultaneous drug release and real-time biosensing of cancer cell viability. This device can reliably monitor impedance signal changes correlated with cell viability while exhibiting excellent properties for both drug encapsulation and on-demand release.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Physical

Electrochemical detection of parathyroid hormone using graphene-incorporated conductive polymer decorated with MoS2 nanoparticles

Ruey-Shin Juang, Chien-Te Hsieh, Chia-Min Liu, Ting-An Lin, Yasser Ashraf Gandomi

Summary: We developed an electrochemical biosensor using reduced graphene oxide (rGO) incorporated onto a conductive polymer poly(3,4-ethoxylenedioxythiophene) (PEDOT) and decorated with molybdenum di-sulfide (MoS2) nanoparticles for the detection of parathyroid hormone (PTH). The sensitivity of the sensors was 0.0011 (mu A center dot mL)/pg with a detection limit of 1.457 pg/mL. The sensors also showed high selectivity towards PTH with the existence of interfering substances diluted to different concentrations.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2023)

Review Engineering, Environmental

Critical Review and Discussion of the Nonlinear Form of Radke-Prausnitz Model in Adsorption Solid-Liquid Phases

Hai Nguyen Tran, Jean-Claude Bollinger, Stefano Salvestrini, Khim Hoong Chu, Ruey-Shin Juang

Summary: The Radke-Prausnitz model, a three-parameter model belonging to the Langmuir-Freundlich-type equation, is analyzed in this study to promote its proper application in adsorption research. The correct expression, citation, and units of its parameters are provided. The model has important implications for understanding adsorption processes.

JOURNAL OF ENVIRONMENTAL ENGINEERING (2023)

Article Engineering, Chemical

Facile synthesis of reusable Ag/TiO2 composites for efficient removal of antibiotic oxytetracycline under UV and solar light irradiation

Chi Hieu Nguyen, Thi Tuong Van Tran, Mai Lien Tran, Ruey-Shin Juang

Summary: Ag-doped TiO2 nanomaterials were prepared using a one-step sol-gel technique. The combination of Ag with TiO2 enhanced the lifetime of photogenerated electron-hole pairs and widened the photocatalytic activity in the visible light region, leading to improved photocatalytic activity.

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2023)

Article Biochemistry & Molecular Biology

A Simplified Kinetic Modeling of CO2 Absorption into Water and Monoethanolamine Solution in Hollow-Fiber Membrane Contactors

Mai Lien Tran, Chi Hieu Nguyen, Kuan-Yan Chu, Ruey-Shin Juang

Summary: This study experimentally confirmed the absorption of carbon dioxide (CO2) from CO2-N2 gas mixtures using water and monoethanolamine (MEA) solution in polypropylene (PP) hollow-fiber membrane contactors. Gas flow occurred inside the module while the absorbent liquid flowed counter-currently outside the shell. Various gas- and liquid-phase velocities as well as MEA concentrations were tested, and the effect of pressure difference between the gas and liquid phases on CO2 absorption was investigated. A simplified mass balance model incorporating the non-wetting mode and overall mass-transfer coefficient was proposed to predict the effective length of the fiber for CO2 absorption. The model also emphasized the significance of membrane wetting when using high concentrations of MEA in the chemical absorption process.

MEMBRANES (2023)

Article Nanoscience & Nanotechnology

Dual pH-/Thermoresponsive Shell-Cross-Linked Magnetic Mesoporous Nanospheres for Doxorubicin Delivery and In Vitro/In Vivo Cancer Treatment

Ndumiso Vukile Mdlovu, Ruey-Shin Juang, Meng-Tzu Weng, You-Sheng Lin, Kuen-Song Lin

Summary: In this study, magnetic nanospheres loaded with doxorubicin were synthesized and evaluated for their therapeutic effects in mice. The results showed that these nanospheres exhibited significant growth inhibition of tumors, indicating their potential for cancer drug delivery.

ACS APPLIED NANO MATERIALS (2023)

Article Chemistry, Physical

Reduced graphene oxide decorated with poly(diallyldimethylammonium chloride) for sensitive detection of acetaminophen in water and human urine samples

Ruey-Shin Juang, Chien -Te Hsieh, Ting -An Lin, Yu -Chia Shao, Yasser Ashraf Gandomi

Summary: In this study, an efficient electrochemical sensor using SPCE modified by rGO-PDDA composites was developed for the detection of acetaminophen with high sensitivity and excellent selectivity. The sensor exhibited a wide concentration range, an ultralow detection limit, and successfully detected acetaminophen in human urine samples.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2023)

Article Chemistry, Multidisciplinary

Hydrothermal synthesis of cobalt germanium oxide supported with carbon-based graphitic carbon nitride for electrochemical determination of ornidazole

Jaysiva Ganesamurthi, Xiang-Ren Chen, Ruey-Shin Juang, Siang -Yu Wei, Da -Yuan Lin

Summary: In this study, a cobalt germanium oxide-graphitic carbon nitride nanocomposite was developed for the electrochemical detection of ornidazole. The nanocomposite exhibited superior selectivity and high sensitivity towards ornidazole, and demonstrated good repeatability and stability in the analysis of real samples.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2023)

Article Engineering, Environmental

Fine structural characterization of noble metals in washcoat of motorcycle three-way converter catalysts

Kuen-Song Lin, Ndumiso Vukile Mdlovu, Ruey-Shin Juang, Mau-Tsu Tang

Summary: In Taiwan, the excessive emissions of pollutant gases from over 14 million motorcycles contribute significantly to air pollution in urban areas. In this study, the fine structures and oxidation states of Pt/Pd/Rh/Ce species in washcoat catalysts of motorcycle catalytic converters were investigated. The results showed that using Pt/Rh/Pd/Ce species on ceria/alumina washcoat effectively controlled the emissions of HCs pollutants through CO exclusion. The presence of an oxygen-rich environment facilitated the oxidation of Rh and Pd species, while the oxidation of Pt species was relatively more difficult. The transition metal in the washcoat catalysts was found to be consistent with the La-O distances at approximately 2.49 angstrom.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Chemistry, Physical

Magnetic/optical assessments of RFeO3 (R=La, Pr, Nd, and Sm) ceramics: An experimental and theoretical discernment

J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia

Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

The effect of Ti-based surface layer on AlSi thin film as a high-performance anode for the lithium-ion battery

Xianxiang Lv, Jing Jin, Weiguang Yang

Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Bifunctional phosphate-modulated Cu2O/CeO2 redox heterojunction: A promising approach for proficient CO2 reduction

Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao

Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Engineering heterogeneous synergistic interface and multifunctional cobalt-iron site enabling high-performance oxygen evolution reaction

Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong

Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Highly efficiency blue emissive from Bi3+ions in zero-dimensional organic bismuth halide for white LED applications

Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang

Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Study on the wear resistance and mechanism of AlCrCuFe2NiTix high-entropy surfacing alloys

Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong

Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Facile synthesis of ternary g-C3N4/polyacrylic acid/CoFe2O4 nanocomposites for solar light irradiated photocatalytic and supercapacitor applications

M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu

Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Investigation on bio-synthesized Ni- and Al-doped cobalt ferrite using lemon juice as eco-fuel

Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad

Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Cu, Ni and Ag ions assisted preparation of nonpolar preferential oriented ZnO films with controlled morphology and optical properties

Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi

Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Characterization of magnetic FeCo particles with controlled bimetallic composition

Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang

Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Micro-alloying effects of Ta and B on nano-oxides and grain boundaries in 13CrWTi-ODS ferritic alloys

Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang

Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Nitrogen-doped reduced graphene oxide/black phosphorus quantum dot composites for electrocatalytic treatment of choroidal melanoma

Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang

Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Significantly enhanced magnetism in cobalt ferrite by manganese and terbium co-doping

Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu

Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

High-performance low-temperature solid oxide fuel cell with nanostructured lanthanum strontium cobaltite/yttria-stabilized zirconia cathode via advanced co-sputtering

Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee

Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Amorphous quaternary alloy nanoplates for efficient catalysis of hydrogen evolution reaction

Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu

Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)