期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 525, 期 -, 页码 191-201出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2012.02.072
关键词
Thermodynamic modeling; Phase diagrams; Thermodynamic properties; Modified Quasichemical Model; Compound Energy Formalism
资金
- National Sciences and Engineering Research Council of Canada (NSERC)
- General Motors of Canada
Critical evaluation and optimization of all available phase diagram and thermodynamic data for the Mn-RE (RE = La, Ce, Pr, Nd and Sm) systems have been conducted to obtain reliable thermodynamic functions of all the phases in the system. In the thermodynamic modeling, it is found that the Mn-RE systems show systematic changes in the phase diagrams and thermodynamic properties such as enthalpy of mixing in liquid state in the order of periodic number in the lanthanide series. This systematic thermodynamic modeling approach for all light RE elements can allow to resolve inconsistencies in the experimental data. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
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