期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 531, 期 -, 页码 59-63出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2012.01.041
关键词
ZnO thin films; Nanorods; Raman spectra; Photoluminescence
资金
- National Natural Science Foundation of China [51001078]
- Zhejiang Provincial Natural Science Foundation of China [Y4110207, Y4110547]
Al and Sb codoped ZnO nanorod ordered array thin films were synthesized on glass substrates with a ZnO seed layer via hydrothermal method with different molar ratios of ammonia/zinc nitrate. It is found that the thin films with molar ratio of 8:1 consist of nanorods growth vertically oriented with ZnO seed layer, and the nanorods with an average diameter of 27.8 nm and a length of 1.02 mu m consist of single crystalline wurtzite ZnO and grow along (0 0 2) plane. Raman scattering analysis demonstrates that the broad peak (similar to 580 cm(-1)) shifts to red direction, while the redshift arrives at a maximum of 15 cm(-1) with molar ratio of 8:1. Room temperature photoluminescence reveals that the increase of emission property of ZnO film is caused by the point defect (Zn-i, V-Zn, V-O, O-Zn) generated due to the adjustment of the molar ratio of ammonia/zinc nitrate. (C) 2012 Elsevier B.V. All rights reserved.
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