4.8 Article

Supramolecular fabrication of multilevel graphene-based gas sensors with high NO2 sensibility

期刊

NANOSCALE
卷 7, 期 22, 页码 10259-10266

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr01770j

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资金

  1. Program for New Century Excellent Talents in University [NCET-10-0035]
  2. National Natural Science Foundation of China [51373005, 21204087]
  3. National Key Basic Research Program of China [2014CB931800]
  4. Fundamental Research Funds for the Central Universities

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This study reports the supramolecular assembly of a silver nanoparticle-naphthalene-1-sulphonic acid-reduced graphene oxide composite (Ag-NA-rGO) and its utilization to fabricate a highly sensitive and selective gas sensor. The prepared supramolecular assembly acted not only as a non-covalent functionalization platform (pi-pi interaction) but was also an excellent scaffold to fabricate a highly sensitive and selective low concentration NO2 gas sensor. The prepared composites were characterized using several techniques, which revealed that the graphene sheets were dispersed as ultrathin monolayers with a uniform distribution of silver nanoparticles. The fabricated multilevel structure exhibited an excellent sensing performance, i.e. 2.8 times better, towards 10 ppm NO2 compared to the NA-rGO and rGO based sensors. Apart from its high sensitivity, superior reversibility and selectivity, the prepared supramolecular assembly exhibited an outstanding linear response over the large concentration range from 1 ppm to 10 ppm. The obtained results demonstrate that the prepared supramolecular assembly holds great potential in the fabrication of efficient and effective low-concentration NO2 gas sensors for practical applications.

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