Article
Chemistry, Applied
Arianna Binello, Giancarlo Cravotto, Janet Menzio, Silvia Tagliapietra
Summary: PAHs, potentially genotoxic and carcinogenic compounds, are mainly derived from incomplete combustion and pyrolysis of organic matter. Coffee, a widely consumed beverage, may contain PAHs due to roasting processes. To ensure the safety of this popular commodity, control over the entire production chain is essential.
Article
Food Science & Technology
Yu-Fang Huang, Po-Lin Liao, Yi-Jun Lin, Shih-Han Huang, Yi-Hsieng Samuel Wu, Chia-Fang Teng, Deng-Jye Yang
Summary: The optimal conditions for simultaneous determination of priority polycyclic aromatic hydrocarbons (PAHs) in coffee beans and coffee brews from the US Environmental Protection Agency (US EPA) and the European Union (EU) were developed. The investigation utilized QuEChERS technology combined with high performance liquid chromatography with temperature-controlled fluorescence detection and gas chromatography tandem mass spectrometry. PAHs were found in commercially available green coffee beans (likely due to environmental contamination) and their presence increased with roasting. Coffee brewed with a coffee machine released more PAHs compared to those brewed with a drip bag. The overall consumption risk of PAHs from the brewed coffee samples was low, but consideration should still be given to reduce PAH intake through the roasting, brewing methods, and amount of consumption.
FOOD RESEARCH INTERNATIONAL
(2023)
Article
Environmental Sciences
Xiaohua Ma, Hao Yang, Shuaidong Li, Changchun Huang, Tao Huang, Hongbin Wan
Summary: The correlation between polycyclic aromatic hydrocarbons (PAHs) and economic parameters in Dianchi Lake, Yunnan province, China, was analyzed, showing significant impact of total population, GDP, energy consumption, etc. An artificial neural network (ANN) model was developed to predict the trend in PAH concentrations in the sediments over the next 10 years. Results indicate the importance of economic and climate factors in increasing pollution levels.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Food Science & Technology
Ying-Chun Wan, Zwe-Lin Kong, Yu-Hsuan Chao, Chia-Fang Teng, Deng-Jye Yang
Summary: This study established good performance conditions for determining EU priority PAHs in coffee samples and evaluated the impact of roasting degree and brewing methods on the PAHs levels in coffee. It was found that coffee machine brewing released higher levels of PAHs compared to general brewing with the drip bag. The consumption risk of PAHs in coffee brews and products is considered to be low.
JOURNAL OF FOOD AND DRUG ANALYSIS
(2022)
Article
Food Science & Technology
Dong Zhang, Xiujuan Li, Zeyu Zhang, Jie Zhang, Qincai Sun, Xiaoliang Duan, Hui Sun, Yanping Cao
Summary: Increasing roasting temperature and time significantly affect the physicochemical properties and chemical composition of vegetable oils, enhancing their antioxidant activities. Roasting also induces some thermal reactions and the formation of certain pollutants to a certain extent.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2022)
Article
Multidisciplinary Sciences
Yusuke Nakakuki, Takashi Hirose, Hikaru Sotome, Min Gao, Daiki Shimizu, Ruiji Li, Jun-Ya Hasegawa, Hiroshi Miyasaka, Kenji Matsuda
Summary: Helically twisted conductive nanocarbon materials are suitable for optoelectronic and electromagnetic molecular devices on the nanometer scale, showing a large effective conjugation length and ultrafast decay dynamics. The extended π-helicenes achieved a large effective conjugation length through helical fusion, leading to an absorption edge in the near-infrared region.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Xiushang Xu, Amy L. Vonder Haar, Rengo Yoshioka, Qizheng Zhang, Serhii Vasylevskyi, Andrew J. Musser, Akimitsu Narita
Summary: A benzo[rst]pentaphene derivative, BPP-MeOPA, was synthesized and characterized by NMR and single-crystal X-ray analysis. Investigation of its photophysical properties, including transient absorption spectroscopy, revealed improved absorption and emission features from an S-1 state with excitonic and charge-transfer character by introducing MeOPA groups.
CHEMICAL COMMUNICATIONS
(2023)
Review
Environmental Sciences
Meng Qiao, Weixiao Qi, Huijuan Liu, Jiuhui Qu
Summary: Oxygenated polycyclic aromatic hydrocarbons (OPAHs) have higher concentrations and toxicity in water environments, posing significant ecological risks to surface water ecosystems.
ENVIRONMENT INTERNATIONAL
(2022)
Article
Chemistry, Organic
Yushi Ohno, Shogo Ando, Daisuke Furusho, Ryoyu Hifumi, Yuuya Nagata, Ikuyoshi Tomita, Shinsuke Inagi
Summary: Here, a facile and selective synthesis of cationic azatriphenylene derivatives was achieved through electrochemical intramolecular cyclization, where the key step involves atom-economical C-H pyridination without a transition-metal catalyst or an oxidant. This proposed strategy provides a practical approach for introducing cationic nitrogen (N (+)) into pi-electron systems, thus expanding the molecular design of N (+)-doped polycyclic aromatic hydrocarbons.
Article
Chemistry, Inorganic & Nuclear
Huimin Zhong, Cong Jiang, Jiahui Zou, Guancheng Zhu, Yanyan Huang
Summary: In this study, CeO2-based porous carbonaceous frameworks (CeO2 PCFs) were used as antioxidant nanozymes to scavenge reactive oxygen species and absorb benzo[a]pyrene. CeO2 PCFs exhibited excellent superoxide dismutase-like and catalase-like activity, effectively eliminating superoxide radical, hydroxyl radical, and hydrogen peroxide. The 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) free radical scavenging assay confirmed the free radical scavenging ability of CeO2 PCFs. Furthermore, CeO2 PCFs with large surface area and porous structure efficiently adsorbed benzo[a]pyrene. The designed CeO2 PCFs can serve as new antioxidant nanozymes for scavenging reactive oxygen species and adsorbing polycyclic aromatic hydrocarbons (PAHs).
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Physical
Thomas Liu, Baptiste Carles, Christine Elias, Claire Tonnele, Daniel Medina-Lopez, Akimitsu Narita, Yannick Chassagneux, Christophe Voisin, David Beljonne, Stephane Campidelli, Loic Rondin, Jean-Sebastien Lauret
Summary: In this study, we conducted single-molecule spectroscopy at cryogenic temperatures to investigate the optical properties of graphene quantum dots (GQDs). We found that temperature has an effect on the spectral characteristics of GQDs, and we used density functional theory calculations to explain these observations. Additionally, we discovered that the vibrational features can serve as a unique fingerprint for identifying GQDs.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Food Science & Technology
Junmin Ji, Yan Zhang, Dan Wang, Yan Wang, Jie Hou
Summary: This study analyzed the hazards and volatile components in sunflower seeds roasted at different temperatures and times. The results showed that the strength of seed-roasting promoted the formation of hazards and increased the contents of polycyclic aromatic hydrocarbons, 3-monochloro-1,2-propanediol esters, and heterocyclic amines in sunflower oil. The volatile components mainly consisted of aldehydes and terpenes, which increased with roasting. However, high intensity roasting resulted in burnt, bitter, and viscosity issues, negatively affecting the sensory quality of the oil. The optimal roasting condition for sunflower seeds was 180-200 degrees C for 15-20 minutes.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2023)
Review
Environmental Sciences
Jamie M. Dearnley, Charles Killeen, Rebecca L. Davis, Vince P. Palace, Gregg T. Tomy
Summary: This article reviews the metabolism and toxicity of polycyclic aromatic compounds (PACs) in fish and presents various methods for analyzing metabolite-containing bile. Recent environmental monitoring studies demonstrate the utility of this technique in assessing oil spill pollution, establishing baseline exposure, and evaluating pollution in urban waterways.
CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2022)
Article
Environmental Sciences
Aliakbar Roudbari, Roshanak Rafiei Nazari, Nabi Shariatifar, Mojtaba Moazzen, Anna Abdolshahi, Solmaz Mirzamohammadi, Masoumeh Madani-Tonekaboni, Mehri Delvarianzadeh, Majid Arabameri
Summary: The study evaluated the health risk and PAHs concentration in tea and coffee samples, finding that contamination levels were generally low and non-carcinogenic. BaP concentration in samples was below EU standards, suggesting control of processing conditions to prevent PAH formation.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Engineering, Environmental
Jiaxing Lu, Jian Zhang, Huijun Xie, Yuming Jing, Mingde Ji, Zhen Hu
Summary: In this study, a novel wastewater treatment process combining sequencing batch reactor, constructed wetland and microalgal membrane photobioreactor (BCM process) was proposed. The process achieved satisfactory removal of polycyclic aromatic hydrocarbons (PAHs) and their substituted derivatives (SPAHs), and significantly reduced bacterial toxicity and genotoxicity. Microalgae played an important role in ensuring water security.
Article
Chemistry, Applied
Sara Noureddine El Moussawi, Reine Karam, Mathieu Cladiere, Hanna Chebib, Rosette Ouaini, Valerie Camel
FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT
(2018)
Article
Chemistry, Applied
Mathieu Cladiere, Gregoire Delaporte, Even Le Roux, Valerie Camel
Article
Chemistry, Applied
Mayela Cepeda-Vazquez, Barbara Rega, Nicolas Descharles, Valerie Camel
Article
Chemistry, Applied
Gregoire Delaporte, Mathieu Cladiere, Delphine Jouan-Rimbaud Bouveresse, Valerie Camel
Article
Automation & Control Systems
Gregoire Delaporte, Mathieu Cladiere, Valerie Camel
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS
(2019)
Article
Food Science & Technology
Gregoire Delaporte, Mathieu Cladiere, Valerie Camel
Article
Chemistry, Applied
Mayela Cepeda-Vazquez, Valerie Camel, David Blumenthal, Barbara Rega
Article
Chemistry, Applied
Sara Noureddine El Moussawi, Rosette Ouaini, Joseph Matta, Hanna Chebib, Mathieu Cladiere, Valerie Camel
Article
Chemistry, Applied
Sara Noureddine El Moussawi, Mathieu Cladiere, Hanna Chebib, Rosette Ouaini, Valerie Camel
FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT
(2019)
Article
Chemistry, Multidisciplinary
Valerie Camel, Marie-Noelle Maillard, Nicolas Descharles, Even Le Roux, Mathieu Cladiere, Isabelle Billault
Summary: The CHIMACTIV website offers extensive educational resources on chemistry safety rules, helping students to enhance learning efficiency and pay more attention to safety regulations through interactive methods.
JOURNAL OF CHEMICAL EDUCATION
(2021)
Article
Chemistry, Multidisciplinary
Valerie Camel, Marie-Noelle Maillard, Jonathan Piard, Cecile Dumas, Mathieu Cladiere, Gerome Fitoussi, Emilie Brun, Isabelle Billault, Cecile Sicard-Roselli
JOURNAL OF CHEMICAL EDUCATION
(2020)
Article
Food Science & Technology
Sara Noureddine El Moussawi, Valerie Camel, Mathieu Cladiere, Nada Lebbos, Hanna Chebib, Rosette Ouaini
JOURNAL OF FOOD PROCESSING AND PRESERVATION
(2020)
Article
Food Science & Technology
Katy Dinis, Lucie Tsamba, Freddy Thomas, Eric Jamin, Valerie Camel
Summary: In this study, apple juice samples from different farming and production processes were analyzed using UHPLC-HRMS. A workflow was developed for data processing, and chemometric tools were employed to discriminate different types of apple juice. Promising results were obtained in identifying potential marker compounds for authentication purposes.
Article
Food Science & Technology
Markus Jungen, Nenad Dragicevic, Miriam Rodriguez-Werner, Simone Schmidt, Katy Dinis, Lucie Tsamba, Eric Jamin, Thorsten Fiedler, Nadine Fischbach, Christof B. Steingass, Valerie Camel, Ralf Schweiggert
Summary: Coumarins, psoralens, and polymethoxyflavones have been used as authenticity markers in lemon juices, but the lack of quantitative concentration limits hinders the differentiation of natural and acceptable variations from unacceptable manufacturing practices or food fraud. In this study, 139 lemon and lime samples from eleven countries were analyzed using different liquid chromatographic methods. After confirming the comparability of the analytical approaches, concentration limits for the differentiation of authentic lemon juices produced under good manufacturing practice conditions from adulterated products were established based on a dataset of 125 samples.
Review
Public, Environmental & Occupational Health
Mathieu Cladiere, Valerie Camel
ENVIRONNEMENT RISQUES & SANTE
(2017)