4.3 Article Proceedings Paper

Electrochemical Behavior of CrN Coated on 316L Stainless Steel in Simulated Cathodic Environment of Proton Exchange Membrane Fuel Cell

期刊

JAPANESE JOURNAL OF APPLIED PHYSICS
卷 47, 期 8, 页码 6887-6890

出版社

IOP PUBLISHING LTD
DOI: 10.1143/JJAP.47.6887

关键词

PEMFC; bipolar plate; CrN coating; potentiodynamic; EIS test

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Four types of CrN coating were deposited on type 316L stainless steel by magnetron sputtering physical vapor deposition (PVD) for use in bipolar plates. Four samples deposited at various bias voltages were evaluated under potentiodynarnic, potentiostatic. and electrochemical impedance spectroscopy (EIS) conditions. EIS data were monitored for 96 h in an aerated corrosive enviromnent at 70 degrees C to determine coating performance at +600mV application. The electrochemical behavior of the coatings was enhanced with decreasing bias voltage. The CrN films on the 316L stainless steel substrate exhibited high protective efficiency, that is. increasing corrosion resistance with decreasing bias voltage. X-ray diffraction (XRD) analysis confirmed the formation of crystalline-refined CrN(200) at a low bias voltage.

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