期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 51, 期 10, 页码 1107-1117出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201100152
关键词
chirality; dendrimers; dendrons; heterochiral; homochiral; racemic; self-assembly
资金
- National Science Foundation [DMR-0548559, DMR-0520020, DMS-0935165, DMR-1066116, DMR-1120901]
- P. Roy Vagelos Chair at Penn
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1120901] Funding Source: National Science Foundation
Self-assembling and self-organizable dendrons, dendrimers, and dendronized polymers produce chiral supramolecular architectures that have been developed as biological mimics. Here we review our work on the self-assembly of homochiral, heterochiral, and racemic dendritic dipeptides, and address one of the most fundamental questions of biological systems: Why are biological systems homochiral and not heterochiral or racemic and, if they were heterochiral or racemic, how would they look and function by comparison with contemporary homochiral biological systems?
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