期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 51, 期 2, 页码 259-274出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201100018
关键词
C-C coupling; epoxidation; homogeneous catalysis; hybrid catalysis; ionic liquids; microwave-assisted reactions; polyoxometalates
Organic inorganic hybrids based on polyoxometalate scaffolds(POMs) are a unique class of molecular metal-oxides featuring a composite surface, whereby the merging of complementary domains stimulates new functions and enhances performances. The interaction between the organic and inorganic components can be designed via covalent and/or non-covalent strategies, yielding novel molecular systems with key applications in catalysis and materials science. Selected examples of such a rewarding approach will be illustrated, including the synthesis of tailored POM-based catalysts, and their application in homogeneous systems and on electrocatalytic surfaces for water splitting and renewable energy production.
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