4.7 Article

Preparation of zirconium-based ceramic and composite fine-grained powders

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ijrmhm.2011.07.015

关键词

Zirconium composite; Particle size; Temperature distribution; Fine powder

资金

  1. Korea institute of Energy Technology Evaluation and Planning (KETEP)
  2. Ministry of Knowledge Economy of the Korean Government [2010T100100392]

向作者/读者索取更多资源

Zirconium-based ceramics and composites such as ZrC, ZrB2, ZrC-SiC, ZrB2-SiC-ZrC, and ZrB2-SiC-ZrC-ZrSi were synthesized in fine powder form via combustion synthesis (CS) using ZrSiO4, Mg, C, B, and NaCl as raw materials. Temperature distributions in the combustion wave were measured by thermocouples and used to estimate the combustion temperature and wave propagation velocity. The influence of the NaCl mole fraction on the combustion parameters, phase composition, and particle size of the composite powders was investigated. The experimental results revealed that the combustion temperature and particle size of the composites have a stable decreasing tendency with increase in the NaCl mole fraction in the starting mixture. It was found that near the combustion limit (1.5 mol NaCl), the combustion temperature drops below 1500 degrees C and the particle size reaches the nanometer scale. (C) 2011 Elsevier Ltd. All rights reserved.

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