期刊
INTERNATIONAL JOURNAL OF PHOTOENERGY
卷 2012, 期 -, 页码 -出版社
HINDAWI LTD
DOI: 10.1155/2012/857345
关键词
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资金
- NSFC [21003021, 20873022, 21173044]
- National High Tech R&D Program of China (863 Program) [2008AA06Z326]
- Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT0818]
- Natural Science Foundation of Fujian Province of China [2010J05024]
- Education Office of Fujian Province of China [JK2010002]
The C-doped CdO photocatalysts were simply prepared by high-temperature solid-state process. The as-prepared photocatalysts were characterized by X-ray powder diffraction (XRD), diffuse reflectance spectroscopy (UV-Vis DRS), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results demonstrated that the carbon was doped into CdO, resulting in the red-shift of the optical absorption of CdO. The photocatalytic behavior of CdO and C-doped CdO was evaluated under the visible light irradiation by using the photocatalytic hydrogen evolution as a model reaction. The C-doped CdO photocatalysts had higher photocatalytic activity over parent CdO under visible light irradiation. The results indicated that the H-2 production was due to the existence of CdS and the enhancement of visible light photocatalytic activity of H-2 production was originated from the doping of carbon into the CdO lattice. The probably reaction mechanism was also discussed and proposed.
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