期刊
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
卷 18, 期 1, 页码 42-47出版社
SPRINGER
DOI: 10.1007/s12613-011-0397-x
关键词
stainless steel; electrochemical impedance spectroscopy; ferrite; austenite; passivation; films
类别
资金
- National Natural Science Foundation of China [50871020]
The passive film formed on 2205 duplex stainless steel (DSS) in 0.5 M NaHCO3+0.5 M NaCl aqueous solution was characterized by electrochemical measurements, including potentiodynamic anodic polarization and dynamic electrochemical impedance spectroscopy (DEIS). The results demonstrate that there is a great difference between the passive film evolutions of ferrite and austenite. The impedance values of ferrite are higher than those of austenite. The impedance peaks of ferritic and austenitic phases correspond to the potential of 0.15 and 0.25 V in the low potential range and correspond to 0.8 and 0.75 V in the high potential range. The evolutions of the capacitance of both phases are reverse compared to the evolutions of impedance. The thickness variations obtained from capacitance agree well with those of impedance analysis. The results can be used to explain why pitting corrosion occurs more easily in austenite phase than in ferrite phase.
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