期刊
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
卷 287, 期 1-3, 页码 16-20出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ijms.2009.03.011
关键词
Nitrenium ion; Ion-molecule reaction; Magnesium cation; Copper cation; FT-ICR
资金
- Merck Research Laboratories
- National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0743258] Funding Source: National Science Foundation
The reactivity of two metallated nitrenium ions toward various substrates was examined in the gas phase. The nitrenium ions were generated by a reaction of benzoyl azide with laser-ablated Mg+ or Cu+ in a Fourier transform ion cyclotron resonance mass spectrometer. The two nitrenium ions show drastically different reactivity. While the Mg-nitrenium ion reacts by radical mechanisms (e.g., H atom abstraction), the Cu-nitrenium ion follows non-radical pathways (e.g., metal ion transfer). (C) 2009 Elsevier B.V. All rights reserved.
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