4.7 Article Proceedings Paper

Trimetallic PdRuNi nanocomposites decorated on graphene oxide: A superior catalyst for the hydrogen evolution reaction

期刊

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 43, 期 38, 页码 17984-17992

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2018.07.122

关键词

Microwave method; Nanocomposite; Outstanding performance; Uniform distribution

资金

  1. Dumlupinar University BAP [2017-40]

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In this work, we report an improved catalyst which is superior to known heterogeneous catalysts for dehydrocoupling Of dimethylamine-borane (DMAB). The prepared three metallic nanocomposites consist of graphene oxide supported monodisperse palladium, ruthenium and nickel nanomaterials (3.78 +/- 0.43 nm). The monodisperse PdRuNi nano particles decorated with graphene oxide (PdRuNi@GO) were synthesized according to the microwave synthesis method and characterized by TEM (Transmisson Electron Microscopy), HR-TEM (High Resolution Transmisson Electron Microscopy), XPS (X-ray photoelectron spectroscopy), XRD (X-ray diffraction) and Raman spectroscopy. The prepared trimetallic nanocomposites have shown outstanding performance and stability as a catalyst for the dehydrocoupling of dimethylamine-borane. To the best of our knowledge, the prepared monodisperse PdRuNi@GO nanoparticles have one of the best catalysts with outstanding TOF (Turnover Frequency) value (737.05 1/h) and E-a (55.47 kJ/mol) (activation energy) among all catalysts prepared for dehydrogenation of dimethylamine-borane at low temperatures. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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