4.7 Article

Visible-light driven photocatalyst (Er3+:YAlO3/Pt-NaTaO3) for hydrogen production from water splitting

期刊

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 39, 期 31, 页码 17608-17616

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2014.08.127

关键词

Pt-supported sodium tantalate (Pt-NaTaO3); Up-conversion luminescence agent (Er3+ :YAlO3); Visible-light photocatalyst; Water splitting; Hydrogen production

资金

  1. National Science Foundation of China [21371084]
  2. Innovation Team Project of Education Department of Liaoning Province [LT2012001]
  3. Public Research Fund Project of Science and Technology Department of Liaoning Province [2012004001]
  4. Shenyang Science and Technology Plan Project [F12-277-1-15, F13-289-1-00]
  5. Science Foundation of Liaoning Provincial Education Department [L2011007]

向作者/读者索取更多资源

NaTaO3 nanoparticles were synthesized by hydrothermal method and then the corresponding visible-light photocatalyst (Er3+:YAlO3/Pt-NaTaO3) was successfully prepared by mixing with Er3+:YAlO3 as up-conversion luminescence agent and supporting Pt as cocatalyst. The prepared Er3+:YAlO3/Pt-NaTaO3 was characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). By studying some influence factors such as Er3+:YAlO3 and Pt-NaTaO3 mass ratio, heat-treated temperature, visible-light irradiation time and solution acidity (pH) on the visible-light photocatalytic hydrogen production caused by Er3+:YAlO3/Pt-NaTaO3, it was found that the prepared Er3+:YAlO3/Pt-NaTaO3 with 0.3:1.0 mass ratio heat-treated at 500 degrees C for 120 min in weak acidic solution (pH = 5.0-6.0) with 5.0 wt% methanol displayed a high photocatalytic activity in hydrogen production from water solution. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

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