Article
Energy & Fuels
Yinsheng Zhang, Xuehua Zou, Haibo Liu, Ye Chen, Shiwei Dong, Minghao Ji, Dong Chen, Chengrui Xu, Heng Xie, Chengzhu Zhu, Steve L. Suib, Tianhu Chen
Summary: Four abundant minerals (Diatomite, Montmorillonite, Halloysite, and Sepiolite) were used to prepare Fe-Ni based catalysts for steam reforming of toluene. The catalyst with diatomite support showed the best catalytic activity, achieving the highest toluene conversion and gas yields at a reaction temperature of 700 degrees C and S/C molar ratio of 1.0.
Article
Chemistry, Physical
Xingyuan Gao, Jangam Ashok, Sibudjing Kawi, Naitao Yang
Summary: A series of LaNi1-xCoxO3 perovskite catalysts were successfully prepared and applied in toluene steam reforming, with LaNi0.8Co0.2O3 showing excellent performance due to the strong interaction between Ni and Co leading to highly dispersed metal, higher reducibility, and abundant active sites.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Jie Ren, Yi-Ling Liu
Summary: In this study, Mg-Al hydrotalcites with tailored morphologies were prepared and supported with Ni for corncob tar reforming. The Ni/MgAl-10 catalyst exhibited excellent activity in syngas production due to its high dispersion of Ni particles, large specific surface area, high reducibility, and high basicity. Compared to other catalysts, Ni/MgAl-10 showed higher stability in steam reforming of toluene, providing insights for designing novel Ni-based catalysts.
Article
Energy & Fuels
Shanhui Zhao, Yunliang Zhang
Summary: In this study, the heterogeneous decomposition and steam/CO2 reforming of gasification tar over bio-char were investigated using experimental and density functional theory (DFT) approaches. The results showed that bio-char significantly enhanced the decomposition of toluene. Steam/CO2 reforming improved toluene decomposition efficiency by maintaining the activity of bio-char. DFT calculations revealed the mechanisms and energy barriers involved in the reactions, providing insights into the role of bio-char.
Article
Chemistry, Physical
Lole Jurado, Vasiliki Papaefthimiou, Sebastien Thomas, Anne-Cecile Roger
Summary: In this study, La-based perovskite-supported Ni materials were synthesized and evaluated for their catalytic performance in tar reforming during biomass gasification. While both Ni/LSCF and Ni-LSCF showed similar catalytic stability and activity in tar reforming, Ni-LSCF exhibited better performance in water gas shift reaction and resistance to coke formation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Engineering, Environmental
Bin Xu, Jianjun Xie, Huacai Liu, Wenshen Yang, Xiuli Yin, Chuangzhi Wu
Summary: In this study, the partial oxidation of toluene as a biomass tar surrogate was investigated in a dielectric barrier discharge (DBD) plasma reactor. The effect of reaction temperature, O2/toluene molar ratio (OTR) and discharge power on performances was studied. The results showed that higher temperatures, OTRs and discharge power led to better performances by promoting toluene destruction and gas product production. Excited N2 species played a crucial role in the process, and the method showed potential for gasification gas purification.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Thermodynamics
Wen Tang, Jing-Pei Cao, Zhi-Hao Wang, Zi-Meng He, Tian-Long Liu, Ze-Ying Wang, Fei-Long Yang, Jie Ren, Xiao-Yan Zhao, Xiao-Bo Feng, Hong-Cun Bai
Summary: The study demonstrates that using acid-washed and oxidized Shengli lignite char as a carbon precursor to load cobalt nano-catalyst shows higher activity and stability in low temperature steam reforming of biomass tar, with relatively high H-2 production and low E-a value.
ENERGY CONVERSION AND MANAGEMENT
(2021)
Article
Chemistry, Analytical
Haimiao Yu, Jiecheng Liu, Haojie Yang
Summary: A novel magnesium slag supported nickel-based catalysts showed higher efficiency in catalytic reforming of volatiles derived from biomass pyrolysis, particularly in tar removal. The catalyst exhibited significantly improved tar conversion rates for cellulose, hemicellulose, and lignin, highlighting its potential for biomass pyrolysis/gasification applications.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2021)
Article
Engineering, Environmental
Yawen Liu, Lina Liu, Xungang Diao, Jie Liang, Chunfei Wu, Yifei Sun
Summary: In this study, Ni-modified ZSM-5 catalysts were prepared using a one-pot hydrothermal synthesis method and used for steam reforming of naphthalene. The effects of reaction temperature, silica-alumina ratio, and metal content on the catalytic performance were investigated. It was found that an appropriate metal content contributes to the catalyst's performance.
Article
Chemistry, Applied
Muhammad Masood Khan, Lijun Jin, Muhammad Mahmood Khan, Yang Li, Hammad Saulat, Yun Zhang, Muhammad Sarfraz, Jialong Zhu, Haoquan Hu
Summary: The addition of activated carbon to Ni/MgO-Al2O3 catalyst improved textural properties, increased surface area and pore volume, and decreased the size of metal Ni. The 10% activated carbon loading in 10AC-Ni/MgO-Al2O3 exhibited the best catalytic activity and stability.
FUEL PROCESSING TECHNOLOGY
(2021)
Article
Chemistry, Applied
Jinglin Gao, Mohsen Shakouri, Yongfeng Hu, Saeed Ghanbari, Catherine Niu, Junjie Liao, Ajay Dalai, Hui Wang
Summary: In the catalytic CO2 reforming of CH4 reaction, the contiguity of the basic sites and metallic sites on the catalysts determines the reaction's activity, selectivity, and stability. Catalysts with different Mg/Al ratios and second metals were prepared and characterized. The size of metallic particles was found to be the main factor determining catalyst performance.
Article
Chemistry, Multidisciplinary
Jie Ren, Fei-Long Yang, Yi-Ling Liu
Summary: This study developed a Ni/MgAl catalyst with excellent activity and stability for toluene conversion, which was further optimized to show remarkable performance in H-2-rich gas production. Characterization and experimental investigations revealed the reaction and deactivation pathways, leading to the identification of the most active catalyst Ni/MgAl-10.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Energy & Fuels
Amir Mosayebi
Summary: This study investigates the kinetic and stability properties of phenol steam reforming reaction under specific temperature and flow rate conditions. The experimental and calculated results show that the kinetic model accurately predicts the experimental hydrogen yield. The stability analysis reveals that the conversion and yields of the catalyst remain stable over a certain period of time before declining.
Article
Chemistry, Physical
Jie Ren, Yi-Ling Liu
Summary: Novel Ni/(Mg, Al)O-x (Ni/MAO) catalysts derived from Ni-Mg-Al hydrotalcites were successfully prepared and used for steam reforming of toluene (SRT), with Ni/MAO-10 exhibiting superior activity and excellent resistance to carbon deposition. The catalyst's high basicity, reducibility, rosette-like morphology, and large specific surface area were confirmed through characterizations, contributing to its exceptional performance in the SRT process.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Analytical
Yishuang Wang, Zhiheng Lu, Mingqiang Chen, Defang Liang, Jun Wang
Summary: Tar formation is a major challenge in biomass gasification, but catalytic steam reforming (CSR) can potentially convert tar into hydrogen. This study successfully prepared a series of NixFeyMn/ATP catalysts and applied them to CSR of toluene, a model tar compound. The addition of trace amounts of Fe and Mn improved the catalyst's stability and activity.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2022)