期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 37, 期 23, 页码 17910-17920出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2012.08.144
关键词
Fuel cell; Pt-carbon catalysts; Vulcan carbon; Carbon nanotubes; Mesoporous carbon
资金
- Universidad Nacional del Litoral (Project CAI+D)
- CONICET [970/09]
- ANPCYT [589/07, PICT 2097, PAE 36985]
The objective of this study is to evaluate different methods to obtain Pt (20 wt%)/carbon electrocatalysts, in order to identify the conditions that lead to electrocatalysts with the best electrochemical performance. This paper involves the study of different methods for the deposition and reduction of H2PtCl6 on three carbon supports: Vulcan carbon, Multiwall carbon nanotubes and mesoporous carbons. The deposition-reduction methods in liquid phase were carried out with HCOOH or NaBH4 as reducing agents. Besides, the conventional impregnation was carried out by deposition of H2PtCl6 on carbon followed by a reduction with H-2 at high temperature. The electrochemical performance of supported Pt catalysts prepared by reduction in liquid phase is strongly dependent on the metallic dispersion, the particle size distribution and the nature of the carbonaceous material used as a support. Results show that the deposition-reduction method using HCOOH 0.3 M at 50-60 degrees C and a mesoporous carbon leads to the most efficient electrocatalyst. Copyright (c) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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