Article
Energy & Fuels
Xiaoqiang Zhang, Lei Wang, Mayken Espinoza, Tingshuai Li, Martin Andersson
Summary: Solid oxide fuel cells (SOFCs) offer high efficiency and flexibility, but face various challenges hindering commercialization. Modeling involves coupling multiple physical fields. Activation-controlled reaction shows highest rate, while diffusion-controlled reactions have lower rates, demonstrating nonlinearity of the model.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Electrochemistry
X. Shen, N. Sinclair, J. Wainright, R. F. Savinell
Summary: The study found issues with traditional Tafel analysis in high-viscosity electrolytes, leading to a proposed extended Butler-Volmer analysis based on modern non-linear fitting techniques for obtaining actual kinetic parameters.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Biochemistry & Molecular Biology
Mariusz Radtke, Christian Hess
Summary: By studying Li-rich and catalytically active gamma-LixV2O5 as a cathode, a direct correlation between Raman shift and Faraday current was observed, which can be used for analysis of Butler-Volmer kinetics. The potential of Raman-aided electrochemical detection method is being discussed.
Article
Environmental Sciences
Dong Ma, Xupicheng Ren, Bo Zhang, Yan Zhao, Guangsheng Qian, Xiaomin Hu
Summary: This study proposed a novel low current density electrochemical technology assisted by peroxymonosulfate (PMS) for the degradation of antibiotics. It has been confirmed that sulfate radical ( SO4 center dot-) could be generated at the boron-doped diamond (BDD) anode in both low and high current conditions. The reaction pathways of ciprofloxacin were also speculated.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Materials Science, Multidisciplinary
B. Wei, D. Legut, S. Sun, H. T. Wang, Z. Z. Shi, H. J. Zhang, R. F. Zhang
Summary: The study presents an improved electrochemical model to investigate the relationship between surface properties and corrosion behaviors, demonstrating the impact of strain energy on electrochemical polarization. Experimental results show that both tensile and compressive strains can lower the corrosion rate, providing a new perspective on understanding the corrosion mechanisms of metals.
MATERIALS & DESIGN
(2021)
Review
Green & Sustainable Science & Technology
A. Raza, K. M. Deen, E. Asselin, W. Haider
Summary: This paper discusses the electrocatalytic behavior of stainless steel in water electrolysis and its potential as a replacement for precious metals electrocatalysts. Surface modification of stainless steel is shown to affect its electrocatalytic ability. The catalytic activity and long-term stability of stainless steels in hydrogen evolution and oxygen evolution reactions are comparable or sometimes better than those of noble electrocatalysts. Overcoming existing challenges such as the lack of active centers and low overall stability could make stainless steel a viable alternative to precious metals electrocatalysts.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2022)
Review
Chemistry, Multidisciplinary
Tongzhou Wang, Xuejie Cao, Lifang Jiao
Summary: The electrochemical oxidation of small molecules for hydrogen production and pollutant degradation has great advantages and potential applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Mia D. Stankovic, Jessica F. Sperryn, Roxanna S. Delima, Connor C. Rupnow, Michael B. Rooney, Monika Stolar, Curtis P. Berlinguette
Summary: Methyltetrahydrofuran (MTHF) can be produced from non-edible biomass as a clean liquid fuel for internal combustion engines. However, the conventional method of electrochemical hydrogenation (ECH) faces challenges in producing MTHF in significant yields. In this study, a membrane reactor is used to successfully produce MTHF through electrochemically-driven hydrogenation of furfural, demonstrating higher selectivity and current densities compared to single-cell ECH. Furthermore, the reaction pathway in the membrane reactor is mapped out, showing a different pathway than in single-cell ECH.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Physical
Jianzhong Liu, Cong Chen, Hongli Wu, Jun Cheng
Summary: This study investigates the oxidation characteristics and control steps of coal particles in carbon-assisted water electrolysis. The results reveal that coal particles mainly undergo indirect oxidation, and the redox reaction between solution catalysts and coal particles is the controlling step in the whole process.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Chemistry, Multidisciplinary
Qizhu Qian, Yin Zhu, Nazir Ahmad, Yafei Feng, Huaikun Zhang, Mingyu Cheng, Huanhuan Liu, Chong Xiao, Genqiang Zhang, Yi Xie
Summary: Electrochemical water splitting powered by renewable energy sources has attracted interest for high-purity hydrogen production, but is hindered by slow electrode reactions. To address this, a hybrid electrochemical water splitting strategy has been proposed, combining favorable electro-oxidation reactions with hydrogen evolution at the cathode. This review summarizes recent developments in alternative oxidation reactions for efficient and cost-effective hybrid water splitting.
ADVANCED MATERIALS
(2023)
Article
Thermodynamics
Min Wang, Liangfei Xu, Xiaofan Yang
Summary: In this study, a new coupled model based on computational fluid dynamics and a 1D model is proposed for accurate and fast prediction of PEM fuel cell performance. The increase in current density is attributed to the increase in consumption rate of hydrogen and oxygen, as well as the increase in membrane water content.
ENERGY CONVERSION AND MANAGEMENT
(2022)
Article
Chemistry, Physical
Merve Gordesel Yildiz, Ozgu Yoruk, Duygu Uysal, Ozkan Murat Dogan, Bekir Zuhtu Uysal
Summary: This study investigated the electrochemical reforming of glycerol for hydrogen production. The performance of the system under different operating conditions was evaluated, and the optimum conditions were determined. The effects of membrane type, pre-treatment procedure, and temperature were studied. The results showed that the maximum hydrogen production was achieved using the Zn/Zn electrode pair, 0.4 M glycerol, and 0.04 M H2SO4 at the anode side, 0.04 M H2SO4 at the cathode side, and pre-treated Nafion XL membrane under room temperature and 2 V potential.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Chemistry, Physical
Jesus Gonzalez-Cobos, Mathieu S. Prevot, Philippe Vernoux
Summary: Lignin electrolysis offers the possibility of co-generating valuable aromatic compounds and green H2 with lower energy cost than traditional water electrolysis. This review provides an overview of anode materials and cells investigated in different conditions and summarizes the remaining challenges. Low-temperature electrolyzers can be integrated in biorefineries for lignin conversion and hydrogen co-generation.
CURRENT OPINION IN ELECTROCHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Diego Oyarzun, Cheng Zhan, Steven A. Hawks, Maira R. Ceron, Helen A. Kuo, Colin K. Loeb, Fikret Aydin, Tuan Anh Pham, Michael Stadermann, Patrick G. Campbell
Summary: This study introduces a multiscale model to investigate ion electrosorption kinetics in porous carbon electrodes, combining quantum mechanical simulations with continuum approaches. The model was experimentally validated and utilized an in-line UV absorption system to provide unprecedented resolution of individual ions in the separation process.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Analytical
Haotian Chen, Richard G. Compton
Summary: The presence of coupled chemistry in electrochemical reactions can significantly impact the observed transfer coefficient, either lowering it below 1 or exceeding 1, resulting in characteristics different from a simple reversible reaction.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Energy & Fuels
Xuemin Zhao, Yunmin Tang, Binglong Zhao, Changning Wu, Junguo Li, Changqing Chu, Ke Liu, Yulong Ding
Summary: The new collector HIP emulsion significantly reduces oil consumption and shows higher flocculation and flotation efficiency compared to kerosene. High-shear pulping promotes the overall flotation rate of HIP emulsion, but may also lead to degradation of its flocculation ability. HIP emulsions are proven to be a potential economic and efficient collector for ultrafine and high-ash content coal slimes beneficiation.
INTERNATIONAL JOURNAL OF COAL PREPARATION AND UTILIZATION
(2022)
Article
Energy & Fuels
Abdullah Naseer Mustapha, Helen Onyeaka, Osaze Omoregbe, Yulong Ding, Yongliang Li
Summary: Latent heat thermal energy storage is an efficient way of storing thermal energy to correct the imbalance between energy production and consumption. A combination of clusters, networks, and bibliometric analyses on an extensive dataset of publications revealed a surge in publications in the field from 2011-2019, coinciding with the passing of energy conservation legislations. China, USA, and Germany lead in total publications, while Turkey leads in average citation per document. The influence of government funding and foreign policy on research outputs of countries, regions, and institutions was also highlighted.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Chemistry, Physical
Ernesto Mura, Yulong Ding
Summary: The study explores the process of a system transitioning from an old phase to a new phase at a first order, introducing the basic principles of nucleation and various factors influencing nucleation, leading readers to understand the complexity of nucleation in dispersed systems.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2021)
Review
Energy & Fuels
Lizhong Yang, Uver Villalobos, Bakytzhan Akhmetov, Antoni Gil, Jun Onn Khor, Anabel Palacios, Yongliang Li, Yulong Ding, Luisa F. Cabeza, Wooi Leong Tan, Alessandro Romagnoli
Summary: This paper comprehensively reviews the research activities about cold thermal energy storage technologies at sub-zero temperatures, including storage materials and their properties, numerical and experimental work summaries, as well as applications analysis and selection criteria.
Article
Engineering, Chemical
Tongtong Zhang, Xiaohui She, Yulong Ding
Summary: LNG regasification and liquid air energy storage (LAES) processes waste a significant amount of energy, which can be recovered to improve efficiency, although this would require additional capital investment and may not always be economically attractive.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2021)
Article
Thermodynamics
Argyrios Anagnostopoulos, Alessio Alexiadis, Yulong Ding
Summary: A novel set of Lennard-Jones parameters for amorphous silica is proposed in this study, capable of accurately simulating the structure. The existence of a compressed liquid layer at the liquid-nanoparticle interface is observed experimentally, with higher density and lower self-diffusivity of the molten salt mixture in proximity to the interface. Ordered distribution of Na+ and K+ ions is indicated at the interface, suggesting the presence of an ordered double-layer.
INTERNATIONAL JOURNAL OF THERMAL SCIENCES
(2021)
Article
Chemistry, Multidisciplinary
Qicheng Chen, Xupan Yang, Yingjin Zhang, Yulong Ding
Summary: The study examined the influence of vacancy defects on the wettability of molten alkali metal salt on the CaO surface using molecular dynamics simulations. The results indicated that higher temperatures and defect concentrations led to poorer wettability of Na2SO4. This was attributed to induced polarization caused by the defect surfaces, ultimately affecting thermal energy transportability at the interface.
Article
Materials Science, Ceramics
Renwei Li, Qicheng Chen, Liang Ouyang, Yingjin Zhang, Binjian Nie, Yulong Ding
Summary: Corrosion prevention is a crucial concern in thermal energy storage, particularly in high-temperature environments. Studying the doped alloy elements revealed that Ti and Mg significantly enhance interfacial bonding strength, while Cr and Ni are ineffective in this aspect. The presence of Mg and Ti atoms at the interface shows an enhancement effect as interfacial binders.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Environmental
Argyrios Anagnostopoulos, Maria Elena Navarro, Maria Stefanidou, Yulong Ding, Georgios Gaidajis
Summary: Red mud is an industrial waste of the aluminum industry, with only 15% currently utilized, but a new method utilizing RM to formulate CPCM has been proposed, showing good performance and suitability for waste heat recovery.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Green & Sustainable Science & Technology
Xing Wang, Xuehui Zhang, Zhitao Zuo, Yangli Zhu, Wen Li, Haisheng Chen, Yulong Ding
Summary: The research shows that the efficiency of an axial turbine in the CAES system decreases nonlinearly with the increase of chamber roughness and can be partially recovered by using a locally smoothed wall with a surface roughness of 1.6 μm on only 11.26% of the wall area. The isentropic efficiency is also increased compared to a full smooth wall when the total pressure ratio is 1.4.
Article
Engineering, Chemical
Shaowu Yin, Peng Kang, Ying He, Li Wang, Chuanping Liu, Lige Tong, Yulong Ding
Summary: The new moving granular bed filter is designed to achieve high-efficiency filtration of fine dust and high performance for different environments, with wide adaptability. This filter demonstrates better dust removal performance, low bed resistance, and high filtration efficiency, maintaining a high filtration efficiency while reducing bed pressure drop effectively.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Energy & Fuels
Yelong Zhang, Qi Miao, Xu Jia, Yi Jin, Zhongbo Li, Linghua Tan, Yulong Ding
Summary: A novel composite TCS material made from MgSO4 and diatomite was reported, showing improved cycle stability, enhanced sorption capacity, and thermal performance in the temperature range of 80-150 degrees C.
Article
Energy & Fuels
Xianglei Liu, Yanan Song, Qiao Xu, Qingyang Luo, Yang Tian, Chunzhuo Dang, Haolei Wang, Meng Chen, Yimin Xuan, Yongliang Li, Yulong Ding
Summary: By developing nacre-like ceramics embedded with titanium nitride nanoparticles, this study successfully achieves efficient solar-to-thermal conversion and rapid energy storage. The combination of high thermal conductivity biomimetic skeletons and volumetric absorptive phase change materials significantly enhances the solar-to-thermal energy storage rate.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2021)
Article
Green & Sustainable Science & Technology
Feng Jiang, Zhiwei Ge, Xiang Ling, Daqiang Cang, Lingling Zhang, Yulong Ding
Summary: The study investigated the utilization of a novel skeleton of modified diatomite-based porous ceramic to load NaNO3 salt and develop shape-stabilized NaNO3. The modified porous ceramic showed superior performance in enhancing the thermal energy storage density and efficiency of shape-stabilized NaNO3, as well as better cycling stability. This research proposed a new strategy for the application of salts-based phase change materials in solar thermal energy storage systems.
Article
Chemistry, Inorganic & Nuclear
M. P. Stockham, B. Dong, M. S. James, Y. Li, Y. Ding, P. R. Slater
Summary: The next generation lithium ion batteries with all solid-state architecture offer higher energy density storage to meet the demands of modern society, particularly the growing electric vehicle market. Although solid state batteries face commercial challenges, garnet materials show promise as potential contenders due to their desirable properties, but there are still obstacles to overcome. Further engineering of Hf systems may lead to additional improvements for future use in solid state batteries.
DALTON TRANSACTIONS
(2021)