Article
Energy & Fuels
Junjie Wen, Yu Xie, Yanping Ma, Haiyang Sun, Huimin Wang, Mo Liu, Qiulin Zhang, Jianjun Chen
Summary: Ni-CeZrAl catalyst prepared by co-precipitation method demonstrated high performance in dry reforming of methane, with the highest methane conversion reaching 38.1%. The superior catalytic behavior was attributed to the high dispersion of surface Ni-0 active phase, abundant oxygen vacancies, and basic sites. In contrast, Ni-CeAl and Ni-CeZr showed inferior catalytic performance due to weak interaction and fewer active sites.
Article
Chemistry, Physical
Jin Wang, Gbolade O. Kayode, Yuki Hirayama, Dina Shpasser, Isao Ogino, Matthew M. Montemore, Oz M. Gazit
Summary: The interaction between supported metals and the support material greatly affects the catalytic performance. In this study, we demonstrate that interfacial sites between two metal oxides, MgAlOx and ZrO2, can enhance the stability and reactivity of nickel nanoparticles. We investigate the effect of metal-support interactions (MSI) in different locations on the performance of dry reforming of methane (DRM). Our results suggest that heterointerfacial sites can be utilized to design DRM catalysts with increased activity and high stability.
Article
Chemistry, Applied
Marco Pizzolato, Giulia Da Pian, Elena Ghedini, Alessandro Di Michele, Federica Menegazzo, Giuseppe Cruciani, Michela Signoretto
Summary: The effects of vanadium promotion on gamma-alumina supported nickel catalysts for methane dry reforming were investigated. The introduction of vanadium was crucial to hinder catalyst deactivation by coke deposition. The formation of nanotubes was reduced and hydrogen yield increased. When coupled with calcium, selectivity toward hydrogen/syngas production was improved. Under concentrated gases, vanadium was fundamental for a higher activity, with an increase of 30% and 15% in CH4 and CO2 conversions compared with the non-doped catalyst.
Article
Chemistry, Physical
Da Hye Song, Un Ho Jung, Young Eun Kim, Hyo Been Im, Tae Ho Lee, Ki Bong Lee, Kee Young Koo
Summary: The dependence of catalytic activity and coke resistance of Ni-based catalysts on the support type was investigated in the dry reforming of methane. It was found that Ni/Al2O3 and Ni/MgO catalysts formed corresponding solid solutions, while MgO-Al2O3 and MgAl2O4 supports suppressed the formation of solid solutions. Ni/MgO-Al2O3 and Ni/MgAl2O4 catalysts showed higher methane conversion rates compared to other catalysts. Moreover, catalysts with higher alkaline-earth metal content exhibited better coke resistance.
Review
Chemistry, Physical
Evandro Alves Nakajima, Ligia Gomes Oliveira, Lazaro Jose Gasparrini, Guilherme Emanuel de Queiros Souza, Antonio Augusto Ignacio, Helton Jose Alves, Carlos Eduardo Borba
Summary: This article investigates the kinetic model for dry methane reforming using Ni/Si-MCM-41 catalysts, with the single-site reversible Langmuir-Hinshelwood model showing the best fit among six models tested. The higher temperatures and lower flow rates resulted in increased methane conversion and hydrogen production, with methane conversions over 85% and H2/CO ratio near 1. The activation energy for the best model was estimated to be 76.6 kJ/mol, demonstrating its potential for mathematical modeling in reactor simulation for syngas or hydrogen-rich gas production.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Robert Franz, Donato Pinto, Evgeny A. Uslamin, Atsushi Urakawa, Evgeny A. Pidko
Summary: This study investigates the use of Ni/Al2O3 catalysts for dry reforming of methane, with a focus on the effects of different promoters on catalyst stability. Higher iron loading on the catalyst leads to lower coke formation during dry reforming. Additionally, promoters with high CO2 affinity can accelerate catalyst oxidation during regeneration, ultimately leading to sintering and increased coke formation. Promoters with significant CO2 interaction are more effective on sintered catalyst samples compared to unpromoted Ni/Al2O3.
Review
Chemistry, Physical
Fariborz Sharifianjazi, Amirhossein Esmaeilkhanian, Leila Bazli, Sara Eskandarinezhad, Samad Khaksar, Parisa Shafiee, Mohammad Yusuf, Bawadi Abdullah, Peyman Salahshour, Farnaz Sadeghi
Summary: This paper reviews the recent advances in Ni- and Co-based nanocatalysts for dry reforming of CH4, including the use of different supports, promoters, and new structures.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Chemistry, Physical
Bernard Chukwuemeka Ekeoma, Mohammad Yusuf, Khairiraihanna Johari, Bawadi Abdullah
Summary: Dry reforming of methane (DRM) is a green alternative for utilizing greenhouse gases and producing syngas. The main limitations of DRM are catalyst sintering and coking. Recent studies have focused on Ni-based catalysts for DRM due to economic constraints on noble metal-based catalysts. Mesoporous silica (MS) supported catalysts show promise due to their high surface areas, thermal stability, and easy availability. However, research on MS as a catalyst support for DRM is still limited.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Engineering, Environmental
Kaihang Han, Yan Wang, Shuo Wang, Qiying Liu, Zhiyong Deng, Fagen Wang
Summary: A novel (Ni/CeO2)@SiO2 catalyst for methane dry reforming (MDR) was investigated using photothermal catalysis to tackle issues of sintering and carbon deposition, leading to higher efficiency and stability in MDR. The band gap energy of ceria was significantly reduced by crystal size, allowing strong absorbance of visible solar light and promoting CH4 and CO2 activation. Additionally, the silica shell confinement effect helped resolve sintering and carbon deposition, ultimately enhancing MDR performance.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Robert Franz, Frans D. Tichelaar, Evgeny A. Uslamin, Evgeny A. Pidko
Summary: The study investigated the impact of passivation on the catalytic performance of Ni/Al2O3 catalysts in dry reforming of methane, showing that changes in conversion and coke content can track sintering of Ni particles. The study also revealed adverse effects of catalyst passivation in excess O2, leading to rapid local overheating and Ni sintering, even at small catalyst scales.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Engineering, Environmental
Tao Xie, Zhen-Yu Zhang, Hao-Ye Zheng, Kai-Di Xu, Zhun Hu, Yu Lei
Summary: Developing new highly efficient catalytic techniques for solar photo-thermal-chemical conversion is crucial. In this paper, a Ni/mesoporous TiO2 photothermal catalyst was prepared and applied to methane dry reforming. Results showed that the prepared catalyst exhibited superior catalytic performance compared to reported catalysts. The synergistic effect of photothermal catalysis significantly improved product formation rates and reactant conversions.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Lei Wang, Ziliang Pu, Yu Shi, Mengmeng Wu, Weidong Shi, Fagen Wang
Summary: In this study, a multifunctional (Ni-Cu/CeO2)@SiO2 catalyst was investigated for photothermal methane dry reforming, demonstrating its superior performance compared to Ni@SiO2. The encapsulation of SiO2 and the metal-support interaction ensured the trace aggregation of Ni and lessened carbon deposition on the used catalyst. This work showcases the potential of photothermal approach for enhancing performance in photosensitive reactions.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Victor Stivenson Sandoval-Bohorquez, Edgar M. Morales-Valencia, Carlos O. Castillo-Araiza, Luz M. Ballesteros-Rueda, Victor G. Baldovino-Medrano
Summary: The study investigates the kinetics of dry reforming using Ni-La2O3 catalyst and suggests that a single active site model is more suitable. Additionally, it is found that CO2 dissociation can have an impact on methane activation.
Article
Chemistry, Physical
Adrian Mizera, Andrzej Kowalczyk, Lucjan Chmielarz, Ewa Drozdz
Summary: Two series of strontium titanates doped with Ni, Co, or Cu were prepared using the wet chemical method, with different stoichiometries. These materials were characterized for their structural properties, possibility of reduction and oxidation reactions, and catalytic properties. Ni-doped samples showed the highest catalytic activity in dry reforming of methane reaction, while Co and Cu-doped samples had minimal catalytic effects. Additionally, a decrease in methane conversion with increasing calcination temperature was observed for Ni-doped strontium titanates.
Article
Chemistry, Physical
Fang Zeng, Juan Zhang, Run Xu, Rongjun Zhang, Jianping Ge
Summary: A highly dispersed Ni catalyst supported by mesoporous SiO2 nanospheres and promoted by alkaline MgO was synthesized and used as an active and stable catalyst for dry reforming of methane (DRM). The Ni/MgO-mSiO(2) catalyst showed superior performance compared to similar catalysts in literatures, with stable CH4 and CO2 conversions around 82% and 85% during 120 hours of DRM reaction. The promotion effect of MgO on the Ni catalyst was systematically studied and found to enhance the dispersion of active centers, inhibit sintering and deactivation of Ni, and facilitate the cracking of CH4, activation of CO2, and elimination of carbon deposits.
Article
Metallurgy & Metallurgical Engineering
N. Marchevsky, M. M. Barroso Quiroga, A. Giaveno, E. Donati
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
(2017)
Article
Chemistry, Physical
Maria M. Barroso Quiroga, Bibiana P. Barbero, Luis E. Cadus
APPLIED CATALYSIS A-GENERAL
(2014)
Article
Engineering, Chemical
C. Garcia-Carvajal, J. Villarroel-Rocha, D. Curvale, M. M. Barroso-Quiroga, K. Sapag
CHEMICAL ENGINEERING COMMUNICATIONS
(2019)
Article
Engineering, Environmental
Maria Martha Barroso Quiroga, Monica Iglesias Junca, Nora Andrea Merino
Summary: Layered double hydroxides (LDH) are anionic clays used as adsorbents, ion exchange materials, and catalysts, with high thermal stability and specific surface areas. LDH synthesized with different combinations showed high removal efficiency of As(III) and As(V) from aqueous solutions, with ZnMgFe removing both species with high efficiency and MgFe showing selectivity for As(V) uptake.
WATER SCIENCE AND TECHNOLOGY
(2021)
Article
Engineering, Chemical
Maria Martha Barroso Quiroga, Adolfo Eduardo Castro Luna
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2007)