Article
Chemistry, Physical
Thanh Son Phan, Doan Pham Minh
Summary: Dry reforming of methane (DRM) is a promising process for producing synthetic gas, and the design of an effective catalyst is crucial. In this study, nickel catalysts supported by calcium hydroxyapatite (HAP) and HAP-doped magnesium (Mg_HAP) were synthesized and evaluated in the DRM reaction. The Ni/HAP and Ni/Mg_HAP catalysts showed outstanding performance due to the tunable acidity-basicity of the supports, strong metal-support interaction, and good thermal stability of nickel nanoparticles. The main products were H2 and CO, with stable selectivity around 85%, while H2O and solid carbon were byproducts with 5-10% selectivity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Thermodynamics
Hamed Rahmati, Atamalek Ghorbanzadeh
Summary: The parallel electrodes gliding plasma (PEGP) is a novel approach for the dry reformation of methane, providing high conversion rates and energy efficiencies. Compared to traditional glide plasma, PEGP demonstrates superior performance in molecular dissociation. By dissipating the energy in the layers of fresh reactants gas instead of overheating or dissociating the products, higher performance is achieved.
Article
Energy & Fuels
R. Bharathi Raja, Anusha C. Halageri, R. Sankar, Ramanujam Sarathi, Ravikrishnan Vinu
Summary: This study investigates the use of non-thermal plasma in a swirl-induced electrode discharge reactor for the dry reforming of methane. The reactor design promotes better mixing of reactant gases, leading to increased conversion rates. The study examines the effect of flow rates and compositions of CO2/CH4 on conversion, and analyzes the characteristics of the produced syngas and solid carbon. The findings show that higher concentrations of CO2 or CH4 result in increased conversion, while increasing flow rates reduce energy costs.
Article
Energy & Fuels
Anh Ngoc T. Cao, Cham Q. Pham, Tung M. Nguyen, Thuan Van Tran, Pham T. T. Phuong, Dai-Viet N. Vo
Summary: Dysprosium (Dy) promoted Co/Al2O3 catalysts with different Dy loadings were synthesized and found to enhance the basicity and activity of the catalysts for methane dry reforming. The addition of Dy reduced the crystallite size of Co3O4, resulting in better metal dispersion and higher catalytic performance. The optimal Dy loading was found to be 0.3 wt%, achieving the highest CH4 conversion and H-2 and CO yields.
Article
Chemistry, Physical
Anh Ngoc T. Cao, Cham Q. Pham, Le Kim Hoang Pham, Dang Le Tri Nguyen, Pham T. T. Phuong, Thi Tuong Vi Tran, Van-Phuoc Nguyen, Thanh Binh Nguyen, Quyet Van Le, Ngoc Anh Nguyen, Tung M. Nguyen
Summary: The metal-support interface plays a crucial role in the dispersion and catalytic activity of catalysts. This study investigated the effect of cerium on cobalt catalyst supported on gamma-alumina and found that cerium promoted the dispersion and reducibility of cobalt, leading to improved conversion of methane and carbon dioxide.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
M. Arapova, E. Smal, Yu. Bespalko, V. Fedorova, K. Valeev, S. Cherepanova, A. Ischenko, V. Sadykov, M. Simonov
Summary: Complex metal-oxide catalysts with doping cations were synthesized by a solvothermal method, showing enhanced activity and stability in ethanol dry reforming reactions. The incorporation of doping cations increased oxygen deficiency, facilitating the implementation of a bifunctional reforming mechanism.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Mohd Razali Shamsuddin, Nurul Asikin-Mijan, Tengku Sharifah Marliza, Manabu Miyamoto, Shigeyuki Uemiya, Mohd Ambar Yarmo, Yun Hin Taufiq-Yap
Summary: Efforts have been made to develop an efficient catalyst for CO2 reforming of CH4 with high activity, cost-effectiveness, and resistance to deactivation. A new bifunctional NiO/dolomite catalyst system showed unique performance in terms of amphoteric sites and self-reduction properties, enhancing CH4 and CO2 conversion without involving a catalyst reduction step.
Article
Chemistry, Physical
Ngoc Thang Tran, Thong Le Minh Pham, Trinh Duy Nguyen, Nguyen Van Cuong, Tan Ji Siang, Pham T. T. Phuong, A. A. Jalil, Quang Duc Truong, Sumaiya Zainal Abidin, Ftwi Y. Hagos, Sonil Nanda, Dai-Viet N. Vo
Summary: The study demonstrated that mesoporous gamma-alumina (gamma-Al2O3) synthesized as a support for Co catalyst showed excellent stability and high performance in methane dry reforming, indicating potential applications in the field.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Alexandra Victoria Tavasoli, Mikaela Preston, Geoffrey Ozin
Summary: A techno-economic model is used to simulate fifteen case studies of a solar dry reforming process, aiming to explore technical challenges associated with its commercial application. The study found that the minimum catalyst activities required for most applications have been demonstrated in the scientific literature over the past two decades, but improvements in photoreactor engineering are needed for practical realization.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Sean Kelly, Elizabeth Mercer, Robin De Meyer, Radu-George Ciocarlan, Sara Bals, Annemie Bogaerts
Summary: We investigated the conversion of CO2 and CH4 in atmospheric pressure microwave plasma, focusing on reaction performance and carbon formation. The energy costs were promising, with the best performance to date for plasma-based dry reforming of methane. The conversion rates for CO2 and CH4 were in the range of 46-49% and 55-67% respectively, producing primarily syngas with H2/CO ratios of 0.6-1.
JOURNAL OF CO2 UTILIZATION
(2023)
Article
Energy & Fuels
Cao-Minh Vo, Anh Ngoc T. Cao, Amjad Saleh Qazaq, Cham Q. Pham, Dang Le Tri Nguyen, Mabkhoot Alsaiari, Tuan V. Vu, Ajit Sharma, Pham T. T. Phuong, Thuan Tran Van, Moustafa A. Rizk, Tung M. Nguyen, Dai-Viet N. Vo
Summary: This work investigated the upgrading of simulated biogas through dry reforming using calcium-promoted cobalt-based catalysts. The study found that the loading of calcium is critical in the catalyst performance, with low dosages resulting in smaller cobalt crystalline size and enhanced reducibility and basicity. The optimal catalyst showed high CH4 and CO2 conversions, as well as suppressed coke formation, leading to improved activity and stability. These findings offer new opportunities to enhance the performance of dry reforming using abundant catalysts.
Article
Materials Science, Multidisciplinary
Fahim Fayaz, Chao He, Avishek Goel, Jukka Rintala, Jukka Konttinen
Summary: Oxidative ethanol dry reforming using 10%Co/Al2O3 catalyst is a promising method to produce high-quality syngas, which can be upgraded to liquid biofuels and chemicals. Increasing the reaction temperature improves the conversion of ethanol and CO2, and yields higher amounts of H2 and CO.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Energy & Fuels
Nurul Asmawati Roslan, Sumaiya Zainal Abidin, Osarieme Uyi Osazuwa, Sim Yee Chin, Y. H. Taufiq-Yap
Summary: This study evaluated the catalytic activity of ruthenium-doped catalysts with different loadings in glycerol dry reforming reactions. The results showed that the 3%Ru-15%Ni/EA catalyst had the best catalytic activity and stability, and it was more coke-resistant compared to other promoted catalysts.
Article
Engineering, Environmental
Lau N. Jun, Mahadi B. Bahari, H. D. Setiabudi, A. A. Jalil, Dai-Viet N. Vo
Summary: This study investigated La-promoted Co/Al2O3 catalysts for Ethylene Glycol-CO2 conversion, with 3%La-promoted catalyst showing the best catalytic performance. La promoted catalysts exhibited excellent physicochemical attributes and significantly reduced carbon deposition.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2021)
Article
Biochemistry & Molecular Biology
Matilde Albano, Luis M. Madeira, Carlos V. Miguel
Summary: Biogas is a valuable renewable energy source that can help reduce greenhouse gas emissions. Through the simulation of membrane reactors, the reforming process of biogas was studied, and it was found that the reaction temperature, pressure, and biogas composition have an impact on hydrogen production.