期刊
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
卷 91, 期 1, 页码 74-86出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/03067310903045448
关键词
fluorescent probe; zinc ions; quinoline; ratiometric
资金
- National Natural Science Foundation of China [J0830415, 20505008, 20675028, 20775023, 20435010]
- '973' National Key Basic Research Programme of China [2007CB310500]
- Hunan Natural Science Foundation [07JJ3025]
A ratiometric fluorescent zinc probe 1 of carboxamidoquinoline with a carboxylic acid group was designed and synthesised. Probe 1 exhibits high selectivity for sensing Zn2+; about a 13-fold increase in fluorescence emission intensity and an 82nm red-shift of fluorescence emission are observed upon binding Zn2+ in EtOH/H2O (1 : 1, V/V) solution. The ratiometric fluorescence response is attributed to the 1 : 1 complex formation between probe 1 and Zn2+ which has been utilised as the basis for the selective detection of Zn2+. The analytical performance characteristics of the proposed Zn2+-sensitive probe were investigated. The linear response range covers a concentration range of Zn2+ from 2.0 x 10(-6) to 5.0 x 10(-5) mol L-1 and the detection limit is 2.7 x 10(-7) mol L-1. The determination of Zn2+ in both tap and river water samples shows satisfactory results.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据