期刊
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
卷 32, 期 15, 页码 1432-1443出版社
WILEY
DOI: 10.1002/er.1459
关键词
ethanol; steam reforming; hydrogen; thermodynamic equilibrium; Gibbs free energy minimization; coke-free region; inert component
资金
- National High Technology Research and Development Program of China [2007AA05Z104, 2006AA05Z115]
- Tianjin Natural Science Foundation [07JCZDJC00200]
- Science & Technology Development Center, SINOPEC of China [X504015]
Thermodynamic equilibrium of ethanol steam reforming has been studied by Gibbs free energy minimization method for hydrogen production in the ranges of water-to-ethanol ratio from 0 to 20, reaction temperature from 400 to 2000 K, pressure from 1 to 60 atm, argon-to-ethanol ratio from 0 to 100. The optimal conditions suitable for the use in molten carbonate fuel cell and solid oxide fuel cell were obtained as follows: 900-1200 K, water-to-ethanol ratio of 3:6, and 1 atm. Under the optimal conditions, complete conversion of ethanol, 60.52-83.58% yield of hydrogen and 32.82-79.60% yield of carbon monoxide could be obtained and no coke forms. Higher pressures have a negative effect, but inert gases have a positive effect, on the hydrogen yield. Coke tends to form at lower temperatures and lower water-to-ethanol ratios. Copyright (c) 2008 John Wiley & Sons, Ltd.
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