4.7 Article Proceedings Paper

Synthesis of bulk glassy Fe-C-Si-B-P-Ga alloys with high glass-forming ability and good soft-magnetic properties

期刊

INTERMETALLICS
卷 18, 期 10, 页码 1821-1825

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.intermet.2010.01.021

关键词

Metallic glasses; Thermal properties; Magnetic properties; Mechanical properties at ambient temperature

向作者/读者索取更多资源

Effects of Ga additions on the glass-forming ability (GFA) and magnetic properties of the Fe76C7.0-Si3.3B5.0P8.7 alloy were investigated. It was found that addition of 1-2% Ga can increase the critical diameter for glass formation from 1 to 3 mm. Moreover, the as-cast alloy containing 1% Ga exhibit good soft-magnetic properties including a high saturation magnetization value of 1.55 T and a low coercive force of 4.9 A/m. The combination of high GFA and good soft-magnetic properties make the newly developed Fe-based bulk metallic glasses promising for electric applications. (C) 2010 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

Competition between continuous and discontinuous precipitation in L12-strengthened high-entropy alloys

J. Y. C. Fang, W. H. Liu, J. H. Luan, T. Yang, Y. Wu, M. W. Fu, Z. B. Jiao

Summary: This study systematically investigates the effects of aging temperature, aging time, and grain size on the CP and DP behaviors of L1(2)-strengthened HEAs. The results show that low temperatures favor the DP reaction, while high temperatures facilitate the CP reaction. At intermediate temperatures, both the CP and DP occur simultaneously and compete with each other. Grain size refinement can promote the DP reaction and result in a DP-dominant microstructure.

INTERMETALLICS (2022)

Article Nanoscience & Nanotechnology

Copper segregation-mediated formation of nanotwins and 9R phase in titanium alloys produced by laser powder bed fusion

Yaojia Ren, Bo Han, Hong Wu, Jianchuan Wang, Bin Liu, Bingqiang Wei, Zengbao Jiao, Ian Baker

Summary: For the first time, the formation of nanotwins and 9R phase were observed in ultrafine-grained Ti-5wt.%Cu alloys with an average lath width of 223 nm produced by laser powder bed fusion. The 9R phase originated from lath boundaries with Cu segregation and terminated at the other boundary of the lath. Deformation caused curvature of the lath boundaries and an increase in lath width, promoting the transition of the central 9R phase to nanotwins. This work provides a new route for in situ production of nanotwinned Ti by the laser melting-induced segregation of Cu.

SCRIPTA MATERIALIA (2023)

Article Materials Science, Multidisciplinary

Heterogenous structure and formation mechanism of white and brown etching layers in bainitic rail steel

Guhui Gao, Miao Liu, Xiaolu Gui, Jie Hu, Junhua Luan, Zengbao Jiao, Xi Wang, Bingzhe Bai, Zhigang Yang

Summary: The failures of conventional pearlitic rail steels are influenced by the formation of hard and brittle white and brown etching layers (WEL and BEL) on the rail raceway during service. This study reports the formation of a unique multilayer heterostructured WEL/BEL in a field-tested bainitic rail. The WEL is composed of fine-grained martensite or ferrite and retained austenite, while the BEL contains nanocrystalline martensite or ferrite, retained austenite, cementite, and oxide or O-rich particles.

ACTA MATERIALIA (2023)

Article Materials Science, Multidisciplinary

Design of ultra-strong but ductile iron-based alloys with low supersaturations

Hao Jie Kong, Tao Yang, Rong Chen, Zengbao Jiao, Tianlong Zhang, Boxuan Cao, Junhua Luan, Shaofei Liu, Anding Wang, Jacob Chih-Ching Huang, Xun-Li Wang, Chain Tsuan Liu

Summary: High-performance, low-cost structural materials with nanoscale precipitations are essential for advanced industry systems. Traditional nucleation mechanisms have limitations in achieving fine dispersion of nanoscale precipitates. However, a revolutionary approach of ultra-strong iron-based alloys has successfully resolved these issues through non-classical nanoscale precipitations and multi-elemental partitioning. This strategy allows for control of nanoscale precipitates with low solute supersaturation, resulting in enhanced strength and ductility, superior fabricability, and post-weld properties.

ACTA MATERIALIA (2023)

Article Engineering, Multidisciplinary

Microstructure evolution and deformation mechanism of coherent L12-strengthened high-entropy alloy during sliding wear

Lu Yang, Chengxia Wei, Dingshan Liang, Feilong Jiang, Zhuo Cheng, Junhua Luan, Zengbao Jiao, Fuzeng Ren

Summary: In this study, the friction and wear behaviors of CoCrNi2(Al0.2Nb0.2) alloy with high-density coherent L1(2) nanoprecipitates during sliding at room and elevated temperatures were systematically investigated. The results showed that the alloy exhibited low wear rate and excellent wear resistance at room temperature, attributed to the precipitation strengthening and dynamic workhardening. At elevated temperature, the reduced wear rates and coefficients of friction were associated with the formation of glaze layer and high resistance to thermal softening. This work provides significant insight into the sliding-induced microstructure evolution and deformation mechanism of L1(2)-strengthened high-entropy alloys during sliding wear.

COMPOSITES PART B-ENGINEERING (2023)

Article Materials Science, Multidisciplinary

Design of FeSiBPCu soft magnetic alloys with good amorphous forming ability and ultra-wide crystallization window

Xingdu Fan, Tao Zhang, Weiming Yang, Junhua Luan, Zengbao Jiao, Hui Li

Summary: The Fe81.3Si4B13-xPxCu1.7 soft magnetic alloys with high Cu and proper P elements addition were synthesized to ensure the amorphous forming ability (AFA) and expand the crystallization window (CW). It was found that an atomic ratio of P/Cu around 3 is advantageous for AFA, and a small amount of P addition promotes the precipitation of alpha-Fe grains. High Cu concentration expands the annealing temperature (Ta) window, while proper P addition enlarges the annealing time (ta) window. The successful synthesis of the Fe81.3Si4B8P5Cu1.7 soft magnetic alloy with a large Ta window of up to 130 degrees C and ta window of 90 min is a breakthrough for nanocrystalline alloys with high saturation magnetization.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2023)

Article Nanoscience & Nanotechnology

Ultrastrong interstitially-strengthened chemically complex martensite via tuning phase stability

Shidong Wang, Jinhua Wang, Yong Yang, Penghui Wang, Shubo Zhang, Junpeng Liu, Zongchang Guo, Hengwei Luan, Chi Zhang, Zengbao Jiao, Zhigang Yang, Gang Sha, Hao Chen

Summary: By tuning the phase stability of interstitial chemically complex alloys (iCCAs), a lath-martensite matrix with a body-centered cubic (bcc) structure was achieved, leading to ultrahigh strength. This alloy design strategy combines the wide chemical composition space and ultrahigh strength of bcc-martensite in steels, providing a new approach for developing high-performance materials.

SCRIPTA MATERIALIA (2023)

Article Multidisciplinary Sciences

Ultra-strong tungsten refractory high-entropy alloy via stepwise controllable coherent nanoprecipitations

Tong Li, Tianwei Liu, Shiteng Zhao, Yan Chen, Junhua Luan, Zengbao Jiao, Robert O. Ritchie, Lanhong Dai

Summary: This article presents a method to enhance the strength of tungsten-based high-entropy alloys by stepwise controllable coherent nanoprecipitations (SCCPs), thus overcoming the trade-off between strength and ductility. The coherent interfaces of SCCPs facilitate dislocation transmission and relieve stress concentrations, resulting in an alloy with ultrahigh strength and ductility.

NATURE COMMUNICATIONS (2023)

Article Materials Science, Multidisciplinary

Achieving superior low-temperature toughness in high-strength low-carbon steel via controlling lath boundary segregation

Xinghao Wei, Lixin Sun, Zhongwu Zhang, Yang Zhang, Junhua Luan, Zengbao Jiao, Chain Tsuan Liu, Gang Zhao

Summary: In this study, the effects of aging treatments at 500 and 550 degrees C on the impact performance of a Cu precipitation-strengthened steel at a low temperature of -80 degrees C were investigated. The main factor controlling the low-temperature toughness was found to be solute segregation at lath boundaries. Excellent impact performance of -180 J at -80 degrees C, along with high yield strength of -1050 MPa and total elongation of 19%, can be achieved by controlling the segregation of solute elements, specifically Mo and Mn, at the lath boundaries. The evolution of matrix and precipitates during aging treatments and the strengthening and toughening mechanisms were also discussed.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2023)

Article Materials Science, Multidisciplinary

Alloying effects on site preference, mechanical properties, and deformation behavior of L12 Co-Ti- based alloys

X. F. Gong, Z. H. Gao, L. P. Nie, S. Qiu, Q. Yu, H. Wu, G. P. Zheng, Z. B. Jiao

Summary: This study systematically investigated the effects of 3d, 4d, and 5d transition elements on the phase stability, mechanical properties, and deformation behavior of L12 Co-Ti-based alloys using first-principles calculations. The results showed that certain transition elements tend to occupy specific sites, reducing the structural stability of the alloys. The analysis also revealed that the strengthening of the alloys is attributed to the strong covalent character of the Co-M bonds. The study provides insights into the fundamental understanding of multicomponent L12 compounds and offers guidelines for designing superior Co-based superalloys.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2023)

Article Engineering, Multidisciplinary

Performance of a Hierarchically Nanostructured W-Cu Composite Produced via Mediating Phase Separation

Chao Hou, Hao Lu, Zhi Zhao, Xintao Huang, Tielong Han, Junhua Luan, Zengbao Jiao, Xiaoyan Song, Zuoren Nie

Summary: The challenge of fabricating nanostructured W-Cu composites has been solved by modulated phase separation. By using intermediary Al, a hierarchically nanostructured W-Cu composite with stable interfaces and high mechanical performance has been achieved.

ENGINEERING (2023)

Article Materials Science, Multidisciplinary

Achieving ultrahigh strength in oxide-dispersion-strengthened CoCrNi alloy via in situ formation of coherent Y-Ti-O nanoprecipitates

Wenhao Mao, Lu Yang, Feilong Jiang, Jiangping He, Junhua Luan, Zengbao Jiao, Fuzeng Ren

Summary: Oxide-dispersion-strengthened CoCrNi alloys were synthesized through in situ oxidation and non-in-situ oxidation methods, resulting in Y-ODS and Y2O3-ODS alloys, respectively. Characterizations using TEM and APT revealed that both alloys consisted of an ultrafine-grained fcc matrix, nanoscale Y-Ti-O precipitates, and a small number of (Cr0.75Ti0.25)2O3 oxides. However, the Y-Ti-O precipitates in the two alloys exhibited different phase and microstructure, with Y2TiO5 and Y2Ti2O7 nanoparticles in Y2O3-ODS and Y-ODS alloys, respectively. The Y-ODS alloy displayed an ultrahigh yield strength of 1660 MPa, 320 MPa higher than the Y2O3-ODS alloy, while maintaining the same ductility. Quantitative analysis revealed that the presence of coherent Y2Ti2O7 nanoprecipitates in the Y-ODS alloy contributed to this significant difference in strength. This study provides valuable insights into the design of ODS high/medium-entropy alloys via in situ oxidation during mechanical alloying and consolidation.

MATERIALS & DESIGN (2023)

Article Materials Science, Multidisciplinary

Nanoscale precipitation, mechanical properties, and deformation behavior of NiAl-strengthened high-strength steels: Effects of Ni and Al contents and ratios

B. C. Zhou, S. F. Liu, H. H. Wu, J. H. Luan, J. M. Guo, T. Yang, Z. B. Jiao

Summary: The effects of Ni and Al contents and ratios on the precipitation, mechanical properties, and deformation behavior of NiAl-strengthened steels were systematically studied. The results show that increasing Ni and Al contents promotes the formation of discontinuous precipitation. The steels with different Ni and Al contents and ratios exhibit high tensile strengths but significantly different ductilities and fracture behaviors. The size of precipitates affects the work hardening capability, with small precipitates enhancing and large precipitates reducing it. Increasing the Ni/Al ratio improves the ductility and fracture behavior of the steels.

MATERIALS & DESIGN (2023)

Article Materials Science, Multidisciplinary

Thermal stability and deformation mechanisms in Ni-Co-Fe-Cr-Al-Ti-Nb-type nanoparticle-strengthened high-entropy alloys

J. X. Hou, J. Y. Zhang, J. X. Zhang, J. H. Luan, Y. X. Wang, B. X. Cao, Y. L. Zhao, Z. B. Jiao, X. J. Liu, W. W. Song, P. K. Liaw, T. Yang

Summary: The precipitation morphologies, coarsening kinetics, elemental partitioning behaviors, grain structures, and tensile properties of L12-strengthened Ni39.9Co20Fe15Cr15Al6Ti4-xNbxB0.1 (x = 0 at.%, 2 at.%, and 4 at.%) high-entropy alloys were investigated. Substituting Ti with Nb resulted in a transition from spheroidal to cuboidal precipitates, increased coarsening kinetics, and phase decomposition at 800°C. Excessive Nb addition led to grain boundary precipitation and phase decomposition from L12 to lamellar-structured D019 phase. Partial substitution of Ti with Nb resulted in a chemically complex and thermally stable L12 phase, ensuring stable phase structure and clean grain boundaries, leading to excellent high-temperature mechanical properties at 700°C.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2023)

Article Chemistry, Physical

Boosting electrochemical performance of Li-S batteries by cerium-based MOFs coated with polypyrrole

Xiaohua Chen, Mi Zhang, Jin Zhu, Juan Wang, Zengbao Jiao, Yong Li

Summary: In this paper, a cathode host for Li-S batteries, Ce-MOF-808@S/PPy composite, was synthesized and tested for its electrochemical performance. The results showed that the composite exhibited improved electrochemical properties, attributed to its unique structure and high specific surface area.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

A novel criterion for predicting the glass-forming ability in Zr-Cu-Al ternary alloys: A molecular dynamics study

M. H. Abbasi, R. Tavakoli, S. G. Shabestari

Summary: The correlation between atomic-scale structure and glass-forming ability of ternary bulk metallic glasses was investigated using molecular dynamics simulation. It was found that the potential energy of the icosahedra reflects the geometric ordering, while the virial stress energy density reveals the chemical ordering. Based on this discovery, a new prediction criterion for glass-forming ability was proposed and validated using experimental data.

INTERMETALLICS (2024)

Article Chemistry, Physical

Tribocorrosion behaviors of Ti-based bulk metallic glass via laser shock peening in 3.5 wt % NaCl solutions

Haimin Zhai, Shuai Cui, Sheng Li, Dongqing He, Bo Cheng, Xinjian Zhang, Wensheng Li, Zhornik Viktor, Uladzimir Seniuts

Summary: Laser shock peening (LSP) treatment significantly affects the phase structure and properties of titanium-based BMG materials, promoting rejuvenation and introducing heterogeneity. This leads to improved plasticity and resistance to crack propagation. LSP-1 specimen exhibits higher hardness and plasticity, reducing fatigue peeling wear caused by brittleness. However, excessive LSP results in increased susceptibility to pitting and significantly reduces tribocorrosion resistance.

INTERMETALLICS (2024)

Article Chemistry, Physical

Stability of intermetallic compounds: Geometrical and topological aspects

Olga A. Blatova, Maria A. Solodovnikova, Ekaterina M. Egorova, Vladislav A. Blatov

Summary: This study applied a universal geometrical-topological approach to analyze the crystal structures of intermetallic compounds deposited in the Inorganic Crystal Structure Database. By exploring the local atomic configurations, they identified different types of coordination polyhedra and proposed criteria for determining geometric instability. This research provides useful indicators for checking crystallographic information and validating structural models.

INTERMETALLICS (2024)

Article Chemistry, Physical

Using multicomponent recycled electronic waste alloys to produce high entropy alloys

Jose M. Torralba, Diego Iriarte, Damien Tourret, Alberto Meza

Summary: The amount of globally recycled e-waste is less than 20% of the total produced. One of the causes for this low recycling rate is the complex and expensive selective sorting of metals. However, recent research has shown that high entropy alloys (HEAs) can be made from complex alloy mixtures, reducing the dependence on pure critical metals. It has been demonstrated that e-waste can be used to produce competitive HEAs.

INTERMETALLICS (2024)

Article Chemistry, Physical

Enhanced mechanical properties of C-doped CuFeMnNi high entropy alloy by modulating phase decomposition

M. Y. He, Y. F. Shen, N. Jia, W. Y. Xue, J. P. Li

Summary: This study successfully improved the mechanical properties of high-entropy alloys (HEAs) through phase decomposition modulation, achieving strengthening of low-cost CuFeMnNi HEAs. The annealed HEAs exhibited excellent mechanical properties, with significantly increased yield strength and maintained satisfactory elongation.

INTERMETALLICS (2024)

Article Chemistry, Physical

In-situ studies of primary nucleation and growth of the cubic Al19Fe4MnSi2 phase in an Al-Fe-Mn-Si metallic glass

D. V. Louzguine-Luzgin, F. R. Pratama

Summary: In this study, the growth rate of a crystalline phase in the Al-Fe-Mn-Si metallic glass was measured in real time using transmission electron microscopy. The effective diffusion coefficient related to the slowest diffusing element (Mn) was estimated. The results showed that the growth rate of the crystalline phase was significantly faster compared to pure Al and AlFe compound.

INTERMETALLICS (2024)

Article Chemistry, Physical

Strong room temperature work hardening in a dual heterogeneous structured ferrous medium entropy alloy

Zhenhua Han, Yubo Tian, Jun Yang, Jianzhao Li, Jinyang Zhang, Gang Liu, Ran Wei, Guojun Zhang

Summary: In this study, a novel medium-entropy alloy (MEA) (Fe65Ni15Cr10Co10)92Ti5Al3 with a dual heterogeneous structure was developed by adding Ti and Al to a previously reported Fe65Ni15Co10Cr10 MEA. The MEA exhibited ultra-high ultimate tensile strength and work hardening extent at room temperature. The addition of Ti and Al induced precipitation and resulted in a continuous FCC -> BCC martensitic transformation and a transformation-induced plasticity effect. The excellent mechanical properties of the alloy were attributed to the synergistic effects of hetero-deformation induced strengthening, precipitation strengthening, and TRIP.

INTERMETALLICS (2024)

Article Chemistry, Physical

Structural rejuvenation and relaxation of a metallic glass under the periodically thermal-mechanical loading

S. Y. Liang, L. T. Zhang, B. Wang, Y. J. Wang, E. Pineda, J. C. Qiao

Summary: This study focuses on the influence of the thermomechanical protocol on the aging or rejuvenation of glass by decoupling the thermal and mechanical processes. The results show that Labased metallic glass exhibits material hypomnesia, with a clearer rejuvenation trend observed after imposing increasing amplitude strain oscillations. There is a threshold value of the oscillation amplitude that separates the effects of the protocol into acceleration of aging or rejuvenation. This study reveals the correlation between the thermomechanical properties of metallic glass and the previous application of strain oscillations of various amplitudes, providing an effective tool for regulating the structural state of metallic glasses through a simple-operated method.

INTERMETALLICS (2024)

Article Chemistry, Physical

Thermal deformation behavior and microstructure evolution of GH141 superalloy during double-cone gradient compression

Chihui Liu, Hua Zhang, Qing Wang, Panzhi Wang, Jiadian Yang, Fanchao Meng, Xin Zhou, Lilong Zhu, Shangzhou Zhang, Liang Jiang

Summary: Thermal deformation behavior and microstructure evolution of GH141 alloy were efficiently studied using high-throughput double-cone gradient compression. Different compression temperatures resulted in a wide gradient equivalent strain distribution and gradient microstructure. The dynamic recrystallization mechanism shifted towards discontinuous dynamic recrystallization with increasing compression temperature.

INTERMETALLICS (2024)

Article Chemistry, Physical

Growth mechanism of highly twinned Al13Fe4 dendrites obtained from a rapidly solidified Al-5at.% Fe melt

D. Dubaux, J. Zollinger, M. -C. de Weerd, J. Ghanbaja, S. Mathieu, S. Migot, P. Boulet, S. Sturm, V. Fournee, M. Sicot, J. Ledieu

Summary: We report the formation of large and highly twinned dendrites of the Al13Fe4 approximant phase embedded in an fcc Al-rich matrix. Using a rapid cooling technique, the approximant appears as a 10-fold dendrite. The grain distributions within the arm are complex and a single dendrite arm can contain up to four different orientations. Three types of twins, namely {100}, {001} and {201} twins, have been identified. A growth mechanism involving heteroepitaxial growth from a decagonal Al-Fe quasicrystalline seed is proposed to explain the formation of these specific 10-fold motifs.

INTERMETALLICS (2024)

Article Chemistry, Physical

Developing centimeter-sized CuZr-based metallic glass composites via multi-element microalloying

Ming Yang, Yibo Zhang, Jie Dong, Yan Huang, Zhichao Lu, Liang Wang, Xuerui Wei, Zhengdong Fu, Jinkui Zhao, Wenli Song, Wei Li, Yuntao Liu, Dong Ma

Summary: A multi-element microalloying strategy has been used to improve the microstructure and mechanical properties of CuZr-based bulk metallic glass composites. Microalloying effectively refines the CuZr phase and results in finely dispersed B2 crystallites embedded in the BMG matrix, leading to the formation of centimeter-sized BMGCs with good mechanical properties.

INTERMETALLICS (2024)

Article Chemistry, Physical

Meso-scopically homogeneous superelastic transformation and related elastocaloric effect in a textured Ti-based shape memory alloy

Xuejie Zhu, Xuexi Zhang, Mingfang Qian, Ziyi Wang, Aibin Li, Zongning Chen, Muhammad Imran, Lin Geng

Summary: The homogeneous superelastic behavior in shape memory alloys (SMAs) is crucial for their functional and structural fatigue properties, as well as their stable elastocaloric effect (eCE). In this study, a Ti-22Nb-4Zr-2Ta plate was prepared with a strong recrystallized texture, resulting in a completely recoverable superelastic strain and narrow hysteresis. The observation of strain and temperature evolution revealed the importance of diffuse transformation and favorable texture in achieving mesoscopically homogeneous transformation and related elastocaloric effect.

INTERMETALLICS (2024)

Article Chemistry, Physical

Increasing ductility via Cu addition in AlxCrFeMnNi: Towards a scrap-based high entropy alloy

Mohammad Navazani, Sitarama Raju Kada, Daniel Fabijanic, Matthew Barnett

Summary: This study investigates the effect of Cu and Al addition on an alloy containing multiple principal elements. The results show that adding small amounts of Cu can improve the alloy's ductility and the hardness of the FCC phase can be predicted using a hybrid model. Unlike previous studies, the corrosion resistance of the alloy is not affected by Cu addition, indicating its potential for further development into a fine-grained stainless steel alloy.

INTERMETALLICS (2024)

Article Chemistry, Physical

The role of Cu addition in the metallurgical features, mechanical properties, and cytocompatibility of cardiovascular stents biodegradable Zn-based alloy

Fatemeh Azizian, Homam Naffakh-Moosavy, Fatemeh Bagheri

Summary: Novel biodegradable Zn-xCu-0.8Mn-0.4Ag alloys were prepared in this study, and the effects of Cu addition and hot extrusion process on microstructure, mechanical properties, and cytotoxicity of the alloys were investigated. The results showed that adding copper and performing a hot extrusion process can significantly improve the mechanical properties of the alloys, making them potential candidates for cardiovascular stents.

INTERMETALLICS (2024)

Article Chemistry, Physical

Thermal stability of Ni3Al microstructure and microhardness after spark plasma sintering

Ivan A. Ditenberg, Denis A. Osipov, Ivan Smirnov, Konstantin V. Grinyaev

Summary: This study investigates the effect of high-temperature annealing on the structural-phase state and microhardness of Ni3Al samples obtained by spark plasma sintering after high-energy ball milling. The results show that certain annealing temperatures promote grain growth and high-density nucleation, leading to the formation of a fine-grained structural state. The study also analyzes the influence of annealing temperature on the strengthening mechanisms.

INTERMETALLICS (2024)