期刊
INORGANICA CHIMICA ACTA
卷 404, 期 -, 页码 167-174出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2013.04.022
关键词
Tridentate ligands; Schiff bases; Transition metals; Template synthesis; X-ray diffraction; Cross-coupling
资金
- Russian Foundation for Basic Research [12-03-00793, 12-03-33107]
Schiff base condensation of o-(thio) phosphorylated anilines with salicylaldehyde affords novel salicylaldimine ligands 1a,b with (thio) phosphoryl pendant arms. Under base-induced deprotonation, 1a, b readily form complexes with Re(I) (2a,b), Pd(II) (3a,b), and Ni(II) (4) ions, featuring kappa(2)-N,O (3a) or kappa(3)-X,N,O (X = O, S) (in the other cases) coordination mode depending on the nature of the substituent X in the P = X moiety. In the absence of a base, the interaction of 1b with (PhCN)(2)PdCl2 yields molecular complex 5 which can be readily transformed into 3b under action of triethylamine. Moreover, complex 3b with the deprotonated form of the ligand can be also readily synthesized by the template assembling of the corresponding aniline and salicylaldehyde on the Pd(II) ion in the presence of Et3N. All the complexes are characterized by spectroscopic techniques (NMR, IR, and Raman) and in some cases by X-ray diffraction analysis. Palladium complex 3b was found to be active (pre)catalyst for the Suzuki cross-coupling of aryl bromides with phenylboronic acid. (C) 2013 Elsevier B. V. All rights reserved.
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