期刊
INORGANICA CHIMICA ACTA
卷 362, 期 10, 页码 3796-3800出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2009.04.044
关键词
Polyoxometalate; Oxidation; Molecular oxygen; Ruthenium
资金
- University Grants Commission
Keggin type undecatungstophospho(aqua) ruthenate(II) was synthesized by the reaction of [PM12O40](3) (aq) and RuCl3 (aq) under mild conditions and characterized by various physicochemical techniques. The catalytic activity of the synthesized complex was evaluated for non-solvent liquid phase oxidation of styrene, cyclohexene and cis-cyclooctene using molecular oxygen. The synthesized complex acts as an efficient catalyst, especially for oxidation of cyclohexene. It shows very high activity for oxidation of cyclohexene in terms of conversion as well as selectivity. It gives 69% conversion with 100% selectivity for cyclohexane oxide. (C) 2009 Elsevier B. V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据