Article
Chemistry, Inorganic & Nuclear
Hyunchul Kwon, Ewa Pietrasiak, Takashi Ohhara, Akiko Nakao, Boknam Chae, Chan-Cuk Hwang, Daesung Jung, In-Chul Hwang, Young Ho Ko, Kimoon Kim, Eunsung Lee
Summary: The synthesis of sandwich-shaped multinuclear silver complexes with planar penta- and tetranuclear wheel-shaped silver units and a central anion is reported. By altering the central anion or adding/removing a silver atom, the size of the silver wheels can be adjusted. NMR mechanistic studies reveal the formation sequence of the silver complexes and provide insights into the dynamics of the self-assembly process.
INORGANIC CHEMISTRY
(2021)
Editorial Material
Chemistry, Multidisciplinary
Marti Gimferrer, Sergi Danes, Eva Vos, Cem B. Yildiz, Ines Corral, Anukul Jana, Pedro Salvador, Diego M. Andrada
Summary: In a recent article, Pan and Frenking challenged our assignment of the oxidation state of low valent group 2 compounds. In our reply, we demonstrate that our assignment of Be(+2) and Mg(+2) oxidation states in Be(cAAC(Dip))(2) and Mg(cAAC(Dip))(2) is consistent with our data and provide numerical proof to refute some of the arguments made by Pan and Frenking. We also argue that indicators based on natural orbitals for chemical valence (NOCV) are more reliable than the criterion of the lowest orbital interaction energy in the energy decomposition analysis (EDA) method.
Article
Chemistry, Physical
Pilankatta K. Ramya, Cherumuttathu H. Suresh
Summary: The structure and energetics of the interactive behavior of Li+ and Li with polycyclic aromatic hydrocarbons (PAHs) were studied. The analysis of the electron distribution in the PAHs led to the categorization of their aromatic rings into five types, and the sextet-type Rs and naphthalene-type Rn rings showed the highest interaction with Li+. The change in the distribution of the electron density at the nucleus of Li+ due to complex formation gave a quantitative measure of the electronic effect of the cation-pi binding. Carbon nanoflake-type systems, including coronene, circumbiphenyl, C42H16, and C50H18, were suggested as good anode materials for lithium ion batteries based on the cell potential prediction.
JOURNAL OF PHYSICAL CHEMISTRY A
(2023)
Article
Polymer Science
Taka-aki Okamura, Kyoko Tsubouchi, Ayumi Okada, Kiyotaka Onitsuka
Summary: Combining chiral ligands with metal ions can create functional spaces similar to those found in biological systems. In this study, silver(I) ions were used to polymerize expanded l-lysine and l-ornithine derivatives, resulting in unique helical structures. The structures of the oligomeric products were determined using DOSY and circular dichroism measurements.
Editorial Material
Chemistry, Multidisciplinary
Zahid Hussain, Yong-an Luo, Yile Wu, Zheng-wang Qu, Stefan Grimme, Douglas W. Stephan
Summary: Interest in main group chemistry related to the Haber-Bosch process is less studied compared to transition metal species. In this study, steric demands in (tBuO(2)CN)(2) hinder the initial interaction of B(C6F5)(3) with nitrogen, leading to the loss of methylpropene and CO2 and the formation of diazene (N2H2) borane adduct 1 and the analogous hydrazine (N2H4) adduct 2. These species react with basic phosphines to form anions of 3 and 5, which contain N2H and N2H3 fragments and serve as metal-free models of plausible intermediates in N-2 reduction.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Takahito Nakajima, Kimihiko Hirao, Bun Chan
Summary: This study generalizes Slater's transition state concept by deriving systematic higher-order transition state approximations, showing that the third-order generalized transition state (GTS3) approximation is a promising alternative due to its balance between accuracy and computational cost.
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Marina Kinzelmann, Johannes Oschwald, Holger Elsen, Vera Warmbrunn, Miriam Hauschild, Sjoerd Harder, Milan Kivala, Thomas Drewello
Summary: The attachment of silver(i) cations to 5,7,12,14-tetraphenyl-6,13-diazapentacene and its reduced dihydro-form has been studied by electrospray ionization mass spectrometry (ESI-MS) and gas-phase collision experiments. Density functional theory (DFT) calculations are used for the structure elucidation of the Ag+ complexes. The oxidation of the reduced dihydro-form by addition of silver(i) cations is accelerated by daylight, and a proposed mechanism for this oxidative dehydrogenation reaction is discussed.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Aleksandra Marciniak, Lorenzo Pacini, Anna Maria Papini, Justyna Brasun
Summary: There is a growing interest in bicyclic peptides among scientists due to their advantageous properties. In this study, a new bicyclic peptide (BCL) was synthesized and its coordination abilities with copper(ii) ions were analyzed. The results showed the formation of both mono- and dinuclear complexes.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Guo-Ling Li, Zhu Zhuo, Bin Wang, Xue-Li Cao, Hai-Feng Su, Wei Wang, You-Gui Huang, Maochun Hong
Summary: This study presents a series of Jr-stacked cages based on hierarchical self-assemblies with pi-stacking interactions, showcasing their versatility in incorporating various species through different hydrogen-bonding modes. The cages are able to stabilize reactive species and encapsulate molecules within their voids, contributing to the construction of diverse hierarchical superstructures. This research provides insights into the chemistry and assembly of supramolecular cages based on pi-pi stacking interactions.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Inorganic & Nuclear
Matthieu Regnacq, Denis Lesage, Marte S. M. Holmsen, Karinne Miqueu, Didier Bourissou, Yves Gimbert
Summary: The study demonstrates the remarkable catalytic ability of (P,C)-cyclometalated Au(iii) complexes in the intermolecular hydroarylation of alkynes. The previous evidence of an outer-sphere mechanism is confirmed through the analysis of experimental data and DFT calculations. The evaluation of critical energies of dissociation of Au(iii) complexes with different substrates using energy-resolved mass spectrometry experiments and kinetic modeling supports the collisional model and its application to particularly fragile adducts.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Ousman Boukar, Jean Jules Fifen, Mama Nsangou, Hassen Ghalila, Jeanet Conradie
Summary: Iron plays a crucial role in biological systems, and the study focuses on the determination of structure and stability of hydrated ferrous ion clusters at different temperatures. New stability rules were proposed, and it was confirmed that hexa-aqua-iron(ii) is in the high spin state. Additionally, the saturated binding energy and clustering energies per solvent molecule were reported.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Multidisciplinary Sciences
Jinghui Luo, Hongzhi Wang, Jinming Wu, Vladyslav Romankov, Nieli Daffe, Jan Dreiser
Summary: Soft X-ray absorption spectroscopy was used to study the interaction between amyloid beta (A beta) peptides and Cu and Zn metal ions. The appearance of Cu(I) was found to be more significant at a basic pH and aggregation resulted in a smaller signature of Cu(I). Different coordination patterns of Cu and Zn ions with nitrogen atoms in the peptides suggest they play different roles in peptide aggregation. This work provides physical insight into the involvement of metal ions and A beta in the formation of toxic reactive oxygen species.
Article
Chemistry, Inorganic & Nuclear
Matthieu Regnacq, Denis Lesage, Marte S. M. Holmsen, Karinne Miqueu, Didier Bourissou, Yves Gimbert
Summary: In this study, the mechanism of (P,C)-cyclometalated Au(iii) complexes catalyzing the intermolecular hydroarylation of alkynes is confirmed through experimental data and theoretical calculations, as well as energy-resolved mass spectrometry experiments and kinetic modeling. The results support the previously proposed collisional model and provide insights into the application of this model on fragile adducts.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Organic
Pilar Elias Elias-Rodriguez, Esteban Matador, Manuel Benitez, Tomas Tejero, Elena Diez, Rosario Fernandez, Pedro Merino, David Monge, Jose M. Lassaletta
Summary: Modulable monosulfonyl squaramides activate gold(I) chloride complexes through H-bonding. Combinations of (PPh3)AuCl or IPrAuCl complexes and an optimal sulfonyl squaramide cocatalyst efficiently catalyze heterocyclizations and a cyclopropanation reaction, while avoiding undesired side reactions. Computational studies suggest that the Au-Cl bond breaks by transligation to the triple bond in a ternary complex formed by the AuCl...HBD catalyst and the substrate.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Chemistry, Organic
Pilar Elias-Rodriguez, Esteban Matador, Manuel Benitez, Tomas Tejero, Elena Diez, Rosario Fernandez, Pedro Merino, David Monge, Jose M. Lassaletta
Summary: Modulable monosulfonyl squaramides activate gold(I) chloride complexes through H bonding in an intermolecular way. The combination of (PPh3)AuCl or IPrAuCl complexes with an optimal sulfonyl squaramide cocatalyst efficiently catalyzes various heterocyclizations and a cyclopropanation reaction. Computational studies reveal that the Au-Cl bond breaks through transligation to the triple bond in a ternary complex formed by the AuCl center dot center dot center dot HBD catalyst and the substrate.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Environmental Sciences
Tamer Shoeib, Glenys M. Webster, Yasmeen Hassan, Sedef Tepe, Melis Yalcin, Cafer Turgut, Perihan Binnur Kurt-Karakus, Liisa Jantunen
SCIENCE OF THE TOTAL ENVIRONMENT
(2019)
Article
Chemistry, Analytical
Mohamed K. Abd El-Rahman, Gloria Mazzone, Amr M. Mahmoud, Emilia Sicilia, Tamer Shoeib
MICROCHEMICAL JOURNAL
(2019)
Article
Environmental Sciences
Hua Wei, Yunong Tang, Tamer Shoeib, Aimin Li, Hu Yang
Article
Multidisciplinary Sciences
Omar S. Bayomie, Haitham Kandeel, Tamer Shoeib, Hu Yang, Noha Youssef, Mayyada M. H. El-Sayed
SCIENTIFIC REPORTS
(2020)
Article
Pharmacology & Pharmacy
Salma El-Shafie, Sherif Ashraf Fahmy, Laila Ziko, Nada Elzahed, Tamer Shoeib, Andreas Kakarougkas
Article
Environmental Sciences
Amandeep Saini, Tom Harner, Sita Chinnadhurai, Jasmin K. Schuster, Alan Yates, Andrew Sweetman, Beatriz H. Aristizabal-Zuluaga, Begona Jimenez, Carlos A. Manzano, Eftade O. Gaga, Gavin Stevenson, Jerzy Falandysz, Jianmin Ma, Karina S. B. Miglioranza, Kurunthachalam Kannan, Maria Tominaga, Narumol Jariyasopit, Nestor Y. Rojas, Omar Amador-Munoz, Ravindra Sinha, Rose Alani, R. Suresh, Takahiro Nishino, Tamer Shoeib
ENVIRONMENTAL POLLUTION
(2020)
Article
Chemistry, Analytical
Mohamed K. Abd El-Rahman, Gloria Mazzone, Amr M. Mahmoud, Emilia Sicilia, Tamer Shoeib
Summary: A highly selective enzyme-free potentiometric ion selective electrode was developed for monitoring Ch(+) in infant formula and milk powders. The method demonstrated fast response time and results that were comparable in accuracy and precision with the traditional enzymatic-spectrophotometric method.
Article
Pharmacology & Pharmacy
Nada Mostafa Aboeita, Sherif Ashraf Fahmy, Mayyada M. H. El-Sayed, Hassan Mohamed El-Said Azzazy, Tamer Shoeib
Summary: This study optimized the ultrasound-assisted extraction technique to extract a highly antioxidant extract from red algae. The extract was then used for the synthesis of copper nanoparticles, which were loaded with nedaplatin to enhance its anticancer effect.
Article
Engineering, Environmental
Boqiang Gao, Qianqian Chang, Zhonghua Xi, Mayyada M. H. El-Sayed, Tamer Shoeib, Hu Yang
Summary: In this study, two environmentally-friendly macroscopically formal (PVF) composited sponges (PL and PLS) functionalized with lignin and lignosulfonate, respectively, were fabricated by a one-step mechanical foaming method. PLS showed a high adsorption capacity for removing seven antibiotics from water, attributed to its large specific surface area and the dominant role of electrostatic attraction in near neutral conditions. These composited sponges have the advantages of simple production, environmental-friendliness, convenient recycle, and low cost, making them potentially viable in treating real wastewater.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Engineering, Environmental
Boqiang Gao, Koukou Tao, Zhonghua Xi, Mayyada M. H. El-Sayed, Tamer Shoeib, Hu Yang
Summary: In this study, a novel 3D lignosulfonate composited PVF sponge impregnated by BiVO4/PANI/Ag ternary photocatalyst was fabricated and showed excellent performance in the adsorption and photodegradation of fluoroquinolones antibiotics. BiVO4/PANI/Ag was well-dispersed and tightly bound to the composited sponge, which efficiently degraded the adsorbed antibiotics through surface photodegradation. The photocatalyst achieved high removal efficiency for all examined antibiotics and maintained a steady performance in continuous dynamic treatment.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Medicinal
Mohamed Korany, Ida Ritacco, Eslam Dabbish, Emilia Sicilia, Tamer Shoeib
Summary: This study aims to develop an effective analytical method for detecting cyclophosphamide and its breakdown products and to elucidate the metabolic pathways of cyclophosphamide. By utilizing mass spectrometry analysis and computation, the reaction mechanism and fragmentation mechanism of cyclophosphamide in its protonated form were revealed. These findings are important for understanding the pharmacological effects and toxicities of cyclophosphamide.
JOURNAL OF CHEMICAL INFORMATION AND MODELING
(2022)
Article
Materials Science, Multidisciplinary
Hassan Mohamed El-Said Azzazy, Amany M. Sawy, Anwar Abdelnaser, Meselhy Ragab Meselhy, Tamer Shoeib, Sherif Ashraf Fahmy
Summary: pH-responsive dual-loaded nanoplatforms based on PAMAM-OH dendrimer show potential for effective treatment of breast cancer, with selective drug release at specific pH conditions and significant cytotoxicity against breast cancer cells.
ACS APPLIED POLYMER MATERIALS
(2022)
Review
Biochemistry & Molecular Biology
Gehane Ghaly, Hatem Tallima, Eslam Dabbish, Norhan Badr ElDin, Mohamed K. Abd El-Rahman, Mahmoud A. A. Ibrahim, Tamer Shoeib
Summary: The rise in cancer incidence and treatment deficiencies have made cancer the second-leading cause of death globally. This has resulted from various factors, including treatment-related side effects, drug resistance, inadequate curative treatment, and tumor relapse. Anti-cancer bioactive peptides (ACPs) are being explored as a potential therapeutic choice due to their high penetration, specificity, and fewer side effects. This review provides an overview of the literature on the conformational structures, modes of action, and membrane interaction mechanisms of ACPs, as well as their successful employment as targeting ligands in cancer treatment. The use of ACPs as a diagnostic tool and their advantages in these applications are discussed, along with approaches for peptide synthesis, reconstruction, and modification. Computational approaches for predicting therapeutic efficacy and suggesting ACP candidates for experimental studies are also highlighted.
Article
Chemistry, Multidisciplinary
Sherif Ashraf Fahmy, Eduard Preis, Alice Abu Dayyih, Mohamed Alawak, Hassan Mohamed El-Said Azzazy, Udo Bakowsky, Tamer Shoeib
Summary: Thermosensitive liposomes have been designed to release chemotherapeutics in a temperature-responsive manner, showing significant anticancer activity in human breast cancer cells.
Proceedings Paper
Nanoscience & Nanotechnology
Sherif Ashraf Fahmy, Jana Bruessler, Fortuna Ponte, Mohamed K. Abd El-Rahman, Nino Russo, Emilia Sicilia, Udo Bakowsky, Tamer Shoeib
APPLIED NANOTECHNOLOGY AND NANOSCIENCE INTERNATIONAL CONFERENCE (ANNIC 2018)
(2019)
Article
Chemistry, Inorganic & Nuclear
Angela Lis, Viorica Gladchi, Gheorghe Duca, Sergey Travin
Summary: This work presents studies on the photochemical transformations of TU and Cys with the addition of Cu(II) or Fe(III) ions. The results show that the oxidation rate of the thiols increases significantly when Cu(II) or Fe(III) ions are added to the system. It has also been found that TU and Cys can form stable complex compounds with the studied metal ions. The oxidation rates of the thiols are found to depend on the radiation intensity and emission spectrum of the irradiation sources.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Cristiane F. A. Teixeira, Estefane I. Teixeira, J. P. C. Nascimento, M. Amilcar Junior, L. M. C. Pinto, Anderson R. L. Caires, G. B. Alcantara, Ana C. Micheletti, Victor M. Deflon, Davi F. Back, Heveline Silva, Lucas Pizzuti, Gleison Antonio Casagrande
Summary: Novel binuclear heteroleptic copper(I) complexes based on mixed DPPE/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. These complexes exhibited similar structural behavior around the Copper(I) atoms and showed promising antimicrobial and anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Chen Chen, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Hai-Mei Qin
Summary: Thermally activated delayed fluorescent (TADF) Cu(I) halide complexes with short lifetimes and intense emissions were synthesized and characterized. These complexes exhibit intense green to yellow-green delayed fluorescence and are suitable for OLED devices.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Tian-Yu Zhang, Xue-Qian Wu, Heng-Yu Ruan, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: In this study, a novel Ni(II)-based metal-organic framework with good electrocatalytic oxidation performance was successfully synthesized, showing potential for direct alcohol fuel cells.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Susanta Das Baishnab, R. N. Dutta Purkayastha, Waldemar Maniukiewicz, Rosa M. Gomila, Antonio Frontera
Summary: The synthesis, structure, and DNA binding ability of three decavanadate complexes containing cationic organic moieties were reported. The complexes were characterized by various techniques and their solid-state structures were analyzed. The complexes showed interesting assembly patterns and exhibited moderately strong intercalative binding with CTDNA. Additionally, their micellization behavior in the presence of the surfactant CTAB was studied.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Jubaraj B. Baruah
Summary: Isomorphous series are generated by replacing atoms or molecules to form materials with similar compositions. They allow modulation of structure and properties, and generate equivalent compositions with novel material properties. The study of stereo-electronic aspects of different equivalent compositions can improve the utility of the original composition.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Kamelah S. Al-Rashdi, Bandar A. Babgi, Ehab M. M. Ali, Bambar Davaasuren, Abdul-Hamid M. Emwas, Mariusz Jaremko, Mark G. Humphrey, Mostafa A. Hussien
Summary: Tridentate ligands were used to synthesize a set of palladium complexes, which were characterized and found to have DNA and BSA binding abilities. The complexes also showed differences in anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Diane Isaacs, Chandler Cox, Mark A. Bezpalko, W. Scott Kassel, William G. Dougherty
Summary: The structure and electrochemical properties of zinc(II) complexes with a face-capping ligand have been investigated, revealing the effect of the ligand on bound semiquinonate (SQ) radicals. The substitution pattern of the SQ ring plays a crucial role in determining the fate of the bound SQ radicals. Additionally, the protective pocket formed by the ligand's phenyl substituents is unable to prevent decomposition of SQ radicals with minimal steric bulk, suggesting that substitution of the SQ ring is the main contributor to their stabilization.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Xingliang Chen, Zhiqiang Jiang
Summary: Here, a series of zinc tetrahedral tetrazolate frameworks (Zn-TTFs) are presented, and it is demonstrated that rotation of carboxyl group can generate structural diversity. Compound 3 exhibits a unique zeolite-like structure, while compound 4 shows both super acid and alkali resistance.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Ankita Puri, Allison Mcaninch, Sheng Shu, Khashayar Rajabimoghadam, Maxime A. Siegler, Marcel Swart, Isaac Garcia-Bosch
Summary: In this article, the synthesis and characterization of copper, nickel, and palladium complexes bound by bidentate ligands derived from ortho-phenylenediamine are described. The complexes contain tunable H-bond donors and their crystal structures reveal intramolecular H-bonding interactions between the ligand scaffolds. Variations in the coordination sphere led to the isolation of the complexes in square-planar or twisted pseudo-tetrahedral geometries. Structural analysis showed that intramolecular H-bonding interactions can be altered by disrupting the bonds between countercations, solvent of crystallization, and ligand scaffold, resulting in changes in the geometry of the complexes. DFT calculations confirmed that Cu complexes prefer twisted geometries while Ni and Pd complexes favor square-planar geometries.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Laiane dos Santos Oliveira, Pedro Henrique de Souza Guarda, Leticia Bazilio Rosa, Gustavo Clauss Rodrigues, Daniele Daiane Affonso, Joao Ernesto de Carvalho, Igor Andrade Santos, Mark Harris, Douglas Hideki Nakahata, Jose Ricardo Sabino, Danilo Ciccone Miguel, Ana Lucia Tasca Gois Ruiz, Ana Carolina Gomes Jardim, Camilla Abbehausen
Summary: Chalcones are chemical precursors of flavonoids that have various biological properties. In this study, novel copper(II)-2'-hydroxy-4-benzyloxychalcone complexes were synthesized and evaluated for their antileishmanial, antiproliferative, and antiviral activities. The results demonstrated that these complexes showed potential effects against tumor cells, leishmania parasites, and SARS-CoV-2 virus. The study also highlighted the influence of ligand structure on biological activity.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Archana Thakur, Harpreet Kaur, Vishal Tyagi
Summary: This review article discusses the findings of research on the 13C NMR spectra of di- and tri-butyltin carboxylates, highlighting the importance of 13C NMR chemical shifts in determining the chemical surroundings of carbon nuclei and their role in structure elucidation.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Qiang Zhao, Qi-Yang Li, Zhi Shen, Guo Zang, Wen-Jun Lv
Summary: In this study, five metal complexes were synthesized using a solvothermal reaction and their structures were analyzed by single crystal X-ray diffraction. Fluorescence and magnetic properties of some complexes were also investigated.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Jeremy Erb, Darcy Setter, Jake Swavey, Frederick Willits, Shawn Swavey
Summary: Three BODIPY-Ru(II) complexes were synthesized by coordinating [Ru(bpy)2Cl]+ complexes to BODIPY ligands. The spectroscopic and electrochemical properties of the complexes were characterized. The complexes exhibited intense absorption peaks due to the pi pi* transitions localized on the BODIPY core, and additional charge transfer transitions associated with the metal center. The complexes showed significant singlet oxygen generation and were able to induce photo-nicking of DNA.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Sahin Reja, Dilip Sarkar, Kaushik Sarkar, Deboshmita Mukherjee, T. K. S. Fayaz, Palash Sanphui, Rajesh Kumar Das
Summary: A promising bioinspired metallocatalyst has been produced and characterized, showing high catalytic activity in oxygen dependant enzymatic radical pathway. The catalyst also exhibits inter and intra molecular H-bonding and C-H-pi interactions.
INORGANICA CHIMICA ACTA
(2024)