期刊
INORGANICA CHIMICA ACTA
卷 362, 期 15, 页码 5275-5277出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2009.09.003
关键词
Tungsten-oxo complex; Tetramer; Crystal structure
资金
- Deutsche Forschungsgemeinschaft
- National Natural Science Foundation of China [20901009/B010202]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
WOCl4 reacts with (Me3Si)(2)O and excess THF to give [WO2Cl2(THF)](4) (1), a new tetrameric tungsten(VI)-oxo complex, which was characterized and crystal structure was determined by X-ray crystallography. Complex 1 has a roughly square planar tetranuclear structure bridged by mu-oxo ligands. Each tungsten atom is coordinated by two bridging oxygens, one terminal oxygen, two axial chlorine atoms and one equatorial O-bonded THF ligand. One of the two mu-oxo ligands is similar to the terminal oxygen atom and the other one is similar to the coordinated oxygen atom of the THF ligand, respectively, which confirmed a previous proposal. Four WO3Cl2(THF) octahedral are associated by sharing corners. Complex 1 is different from three known tetrameric tungsten analogues in its structural arrangement and properties. (C) 2009 Elsevier B. V. All rights reserved.
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