期刊
INORGANICA CHIMICA ACTA
卷 361, 期 7, 页码 1861-1867出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2007.09.043
关键词
2,2'-biphospholes; diphosphines; diphosphinites; stereodynamic ligands; enantiopure platinum complexes; hydroformylation
Enantiopure platinum(II) complexes have been synthetized with chiral stereodynamic diphosphine and diphosphinite ligands derived from 2,2-biphosphole through a dynamic chirality control upon coordination. Catalytic performances of these platinum complexes have been explored in asymmetric hydroformylation. All complexes proved to be effective catalysts with respect to chemoselectivity and regioselectivity but induced only low enantioselectivities. (c) 2007 Elsevier B.V. All rights reserved.
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