4.7 Article

Synthesis, structure and luminescence property of Eu(III) metal-organic framework based on 2,2′-bipyridine-5,5′-dicarboxylic acid

期刊

INORGANIC CHEMISTRY COMMUNICATIONS
卷 46, 期 -, 页码 39-42

出版社

ELSEVIER
DOI: 10.1016/j.inoche.2014.04.037

关键词

Metal organic frameworks; Lanthanide; Thermal stability; Luminescent

资金

  1. National Natural Science Foundation of China [21371060, 51073061, 21174044]
  2. China Postdoctoral Science Foundation [2012M510198]
  3. Fundamental Research Funds for the Central Universities [2011ZZ0011]
  4. 973 Program [2012CB025902]
  5. Pearl River in Guangzhou City of Nova of Science and Technology Special Funded Projects [2014J2200047]
  6. Guangdong Province of Science and Technology of China [2010B090400495]

向作者/读者索取更多资源

A novel trivalent europium, Eu(III), 2,2'-bipyridine-5,5'-dicarboxylic acid (bpdc) metal-organic framework, namely, [Eu-4(bPdc)(5)(CH3NH2)(3)(DMSO)(H2O)] 1 was synthesized by the solvothermal reaction of bpdc with trivalent Eu(III) salts in a mixed solvent system containing N,N'-dimethylformamide (DMF) and dimethyl sulfoxide (DMSO). The single X-ray diffraction indicated that complex 1 had a novel porous three-dimensional framework with two different binuclear metal units. The photoluminescence spectrum of the complex displayed strong emission maxima at 472 and 618 nm. (C) 2014 Elsevier B.V. All rights reserved.

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