期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 14, 期 12, 页码 1911-1914出版社
ELSEVIER
DOI: 10.1016/j.inoche.2011.09.009
关键词
Polyoxometalate; Double templates; Cu-3-triad triangular unit; Electrochemical property
资金
- National Natural Science Foundation of China [21071029]
A novel double-Dawson-anion-templated, triangular trinuclear Cu-trz unit-based metal-organic framework [Cu-8(II)(trz)(6)(mu(3)-O)(2)(H2O)(12)][P2W18O62]center dot 4H(2)O (1) (Htrz=1,2,4-triazole), has been hydrothermally synthesized and characterized by routine methods. Compound 1 is the first example of the Cu-3-triad triangular unit-based three-dimensional (3D) metal-organic framework templated by double [P2W18O62](6-) polyoxoanions. Furthermore, the electrochemical property of compound 1 has been studied. (C) 2011 Published by Elsevier B.V.
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