期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 13, 期 1, 页码 211-214出版社
ELSEVIER
DOI: 10.1016/j.inoche.2009.11.027
关键词
CuCN; Tetrazole; Supramolecular framework; Interpenetration; Luminescence
资金
- National Natural Science Foundation of China [20801033, 20871079]
- Natural Science Foundation of Shaanxi Province [2009JQ2003]
- Youth Foundation of School of Chemistry and Materials Science
The sell-assembly of CuCN and 1H-TAZ ligand under hydrothermal conditions generated a novel three-dimensional hybrid supramolecular framework, namely, [Cu-6(TAZ)(4)(CN)(2)](n) (1) (TAZ = tetrazole). Single-crystal X-ray diffraction show that [Cu-2(TAZ)(2)] binuclear subunits are linked by mu(2)- and mu(3)-CN groups to give a 2D double-wave-shaped network, which possesses 1D channels with four open-windows. The 2D bilayers interpenetrated each other to form the 3D supramolecular framework of 1. (c) 2009 Elsevier B.V. All rights reserved.
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