期刊
INORGANIC CHEMISTRY
卷 53, 期 20, 页码 11068-11074出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic5015797
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资金
- National Natural Science Foundation of China [21171162, 21273063]
- Jilin Province Youth Foundation [20130522132JH]
- SRF for ROCS (State Education Ministry)
- Program for New Century Excellent Talents in University [NCET-11-0958]
A family of di-, tri-, and tetranuclear copper(I) complexes supported by length-controlled silaamidinate ligands have been synthesized to show short Cu-I-Cu-I distances (2.43-2.62 angstrom) and feature a linear or bent metal-metal arrangement, which is elucidated by a relativistic density functional theory calculation.
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