期刊
INORGANIC CHEMISTRY
卷 53, 期 19, 页码 10094-10100出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic500840e
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资金
- FedEx Institute of Technology
- NSF EPS [1004083, CHE 0955723, CHE 0911528]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1543490] Funding Source: National Science Foundation
- EPSCoR
- Office Of The Director [1004083] Funding Source: National Science Foundation
Previous studies of Co catalysts for H-2 evolution have shown opposite effects between the redox potentials of Co centers and their catalytic properties such as the overpotential and turnover frequency: Co catalysts with more positive reduction potentials from structural modification display insignificant changes in the overpotential for H-2 evolution and require stronger acid for catalysis, and Co catalysts with lower overpotentials show decreased turnover frequency for H-2 evolution. In order to explore the electronic effects of a ligand scaffold on the catalytic properties for H-2 evolution by a Co complex with a pentadentate ligand, N,N-bis(2-pyridinylmethyl)-2,2'-bipyridine-6-methanamine (DPA-Bpy), we replaced the pyridyls in DPA-Bpy with more basic isoquinoline groups. In contrast to data from previously reported studies, in the current study, a Co complex with a more positive reduction potential, resulting from the replacement of pyridyls with isoquinoline groups, leads to a lower overpotential and higher turnover frequency for both electro- and photocatalytic H-2 production in neutral aqueous solution.
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