期刊
INORGANIC CHEMISTRY
卷 53, 期 14, 页码 7170-7180出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic501196q
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资金
- Japan Society for the Promotion of Science (JSPS) [24107005]
- Grants-in-Aid for Scientific Research [25810036, 24107005] Funding Source: KAKEN
We successfully developed selective synthesis of strongly emissive ring-shaped Re(I) multinuclear complexes (RnP(x)(n+) in Chart I) with much higher yields compared with the previously reported method. This improved method could also be employed to prepare a novel ring-shaped multinuclear complex composed of structurally different Re(I) units. Each Re unit in RnP(x)(n+) could electrochemically accept one electron, and the multielectron reduced states of RnP(x)(n+) were stable. In the presence of triethanolamine, the ring-shaped tetranuclear and hexanuclear complexes can be photochemically reduced and accumulate 2.9-3.6 and 4.4 electrons in one molecule, respectively.
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