期刊
INORGANIC CHEMISTRY
卷 50, 期 17, 页码 8502-8508出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic201096c
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资金
- Deutsche Forschungsgemeinschaft [Ro 224/55-3, DI 921/3-2]
- Alexander von Humboldt Stiftung
Reactions of N-heterocyclic carbene stabilized dichlorosilylene IPr center dot SiCl2 (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with (eta(5)-C5H5)V(CO)(4), (eta(5)-C5H5)Co(CO)(2), and Fe-2(CO)(9) afford dichlorosilylene complexes IPr center dot SiCl2 center dot V(CO)(3)(eta(5)-C5H5) (2), IPr center dot SiCl2 center dot Co(CO)-(eta(5)-C5H5) (3), and IPr center dot SiCl2 center dot Fe(CO)(4) (4), respectively. Complexes 2-4 are stable under an inert atmosphere, are soluble in common organic solvents, and have been characterized by elemental analysis and multinudear (H-1, C-13, and Si-29) NMR spectroscopy. Molecular structures of 2-4 have been determined by single crystal X-ray crystallographic studies and refined with nonspherical scattering factors.
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