期刊
INORGANIC CHEMISTRY
卷 50, 期 19, 页码 9284-9289出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic200540c
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资金
- National Natural Science Foundation of China [20971098, 21031002]
- Program for New Century Excellent Talents in University [NCET-07-0613]
- Tianjin Natural Science Foundation [10JCZDJC21800]
- Tianjin Normal University [52X09004]
By using different organic acids as additive agents, hydrothermal reactions of AgNO3 with 3,5-bis(2-pyridyl)-4-amino-1,2,4-triazole (2-bpt) lead to formation of two conformational polymorphs of [Ag(2-bpt)](NO3) with bimetallocyclic and 1-D helical coordination patterns. Interconversion between the two supramolecular isomers can be achieved under proper conditions, which will pass through the same intermediate state.
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