期刊
INORGANIC CHEMISTRY
卷 50, 期 12, 页码 5339-5341出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic2006869
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资金
- MIGINN (Spain)
- FEDER [CTQ200760808/BQU]
- Fundaciem Seneca [04539/GERM/06, 03059/P1/05]
Iodine and the pincer complex [Pd(O,N,C-L)I], where L is the monoanionic ligand resulting from deprotonation of the acetyl group of the dimethylmonoketal of 2,6-diacetylpyridine, are in equilibrium at low temperatures with the palladium(IV) complex [Pd(O,N,C-L)I-3], which can be isolated at -40 degrees C and characterized by H-1 NMR spectroscopy and X-ray diffraction studies, in spite of its great instability. When the same reaction is carried out at room temperature, a quantitative reductive elimination process occurs, giving L-I, which in the presence of water affords L'1, resulting from hydrolysis of L-I.
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